Copper's Contribution to Amination Catalysis

被引:56
作者
Chemler, Sherry R. [1 ]
机构
[1] SUNY Buffalo, Dept Chem, Buffalo, NY 14260 USA
关键词
ULLMANN; CYCLOADDITION; COMPLEXES; HALIDES;
D O I
10.1126/science.1237175
中图分类号
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号
07 ; 0710 ; 09 ;
摘要
Copper complexes catalyze a remarkably broad range of organic reactions that form carbon-nitrogen bonds.
引用
收藏
页码:624 / 626
页数:3
相关论文
共 19 条
[1]   Transition-Metal-Catalyzed Alkylations of Amines with Alkyl Halides: Photoinduced, Copper-Catalyzed Couplings of Carbazoles [J].
Bissember, Alex C. ;
Lundgren, Rylan J. ;
Creutz, Sidney E. ;
Peters, Jonas C. ;
Fu, Gregory C. .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2013, 52 (19) :5129-5133
[2]   The role of organometallic copper(III) complexes in homogeneous catalysis [J].
Casitas, Alicia ;
Ribas, Xavi .
CHEMICAL SCIENCE, 2013, 4 (06) :2301-2318
[3]   Tuneable asymmetric copper-catalysed allylic amination and oxidation reactions [J].
Clark, JS ;
Roche, C .
CHEMICAL COMMUNICATIONS, 2005, (41) :5175-5177
[4]   Photoinduced Ullmann C-N Coupling: Demonstrating the Viability of a Radical Pathway [J].
Creutz, Sidney E. ;
Lotito, Kenneth J. ;
Fu, Gregory C. ;
Peters, Jonas C. .
SCIENCE, 2012, 338 (6107) :647-651
[5]   Copper-Catalyzed sp3 C-H Amination [J].
Gephart, Raymond T., III ;
Warren, Timothy H. .
ORGANOMETALLICS, 2012, 31 (22) :7728-7752
[6]   Catalytic asymmetric conjugate addition and allylic alkylation with Grignard reagents [J].
Harutyunyan, Syuzanna R. ;
den Hartog, Tim ;
Geurts, Koen ;
Minnaard, Adriaan J. ;
Feringa, Ben L. .
CHEMICAL REVIEWS, 2008, 108 (08) :2824-2852
[7]   Chiral bis(oxazoline) copper(II) complexes: Versatile catalysts for enantioselective cycloaddition, aldol, Michael, and carbonyl ene reactions [J].
Johnson, JS ;
Evans, DA .
ACCOUNTS OF CHEMICAL RESEARCH, 2000, 33 (06) :325-335
[8]   Computational Explorations of Mechanisms and Ligand-Directed Selectivities of Copper-Catalyzed Ullmann-Type Reactions [J].
Jones, Gavin O. ;
Liu, Peng ;
Houk, K. N. ;
Buchwald, Stephen L. .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2010, 132 (17) :6205-6213
[9]   A general and efficient copper catalyst for the amidation of aryl halides [J].
Klapars, A ;
Huang, XH ;
Buchwald, SL .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (25) :7421-7428
[10]   Renaissance of Ullmann and Goldberg reactions - Progress in copper catalyzed C-N-, C-O- and C-S-coupling [J].
Kunz, K ;
Scholz, U ;
Ganzer, D .
SYNLETT, 2003, (15) :2428-2439