Azulenic β diketones.: Synthesis, properties and reactions to form five membered aromatic heterocycles

被引：7

作者：

Razus, Alexandru C. ^{[1
]}

Birzan, Liviu ^{[1
]}

Nae, Stefania ^{[1
]}

Lehadus, Oana Luiza ^{[1
]}

Pavel, Claudia ^{[1
]}

Costan, Oana ^{[1
]}

机构：

[1] Romanian Acad, Inst Organ Chem CD Nenitzescu, Spl Independentei 202 B,POB 15-254, Bucharest 060023, Romania

来源：

ARKIVOC | 2005年

关键词：

azulene; beta-diketone; pyrazole; isoxazole;

D O I：

10.3998/ark.5550190.0006.a07

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Azulenic beta-diketones were synthesized in the reaction of different beta-diketones with 1-azulenecarboxylic acid chloride, in the presence of MgCl2 and pyridine, as a result of condensation and subsequent acyl elimination. The obtained dicarbonyl compounds were used for the generation of azulenic pyrazoles and isoxazoles. The structures and some physicochemical properties of the obtained products were reported.

引用

页码：71 / 85

页数：15

共 24 条

[1] ABE N, 1973, TETRAHEDRON LETT, P3883
[2] Azulene-containing donor-acceptor compounds as second-order nonlinear chromophores
Asato, AE
Liu, RSH
Rao, VP
Cai, YM
[J]. TETRAHEDRON LETTERS, 1996, 37 (04) : 419 - 422
[3] CHERKASOVA LV, 1970, KHIM GETEROTSIKL, P1452
[4] CRISTIAN L, 2004, IN PRESS CHEM MAT
[5] DOROFEYENKO GN, 1980, KHIM GETEROTSIKL+, P1045
[6] Molecules with potential applications for non-linear optics: the combination of ferrocene and azulene
Herrmann, R
Pedersen, B
Wagner, G
Youn, JH
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1998, 571 (02) : 261 - 266
[7] beta-diketones: Synthesis, structure and bactericidal properties
Hurd, CD
Kelso, CD
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1940, 62 : 2184 - 2187
[8] Push-pull azulene-based chromophores with nonlinear optical properties
Iftime, G
Lacroix, PG
Nakatani, K
Razus, AC
[J]. TETRAHEDRON LETTERS, 1998, 39 (38) : 6853 - 6856
[9] Acid-catalyzed condensation of azulenes with 9-anthracenecarbaldehyde and the synthesis of (9-anthryl)di(1-azulenyl)methyl and (1-azulenyl)[10-(1-azulenyl)-9-anthryl]methyl hexafluorophosphates
Ito, S
Fujita, M
Morita, N
Asao, T
[J]. BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 2000, 73 (03) : 721 - 727
[10] KRIVUN SV, 1971, KHIM GETEROTSIKL+, P1320

← 1 2 3 →