Compartmentalisation in miniemulsions:: Exploration of compartmentalisation and some interesting end-uses

被引：3

作者：

Ouzineb, K

Graillat, C

Dubé, MA

Jovanovic, R

McKenna, TF ^{[1
]}

机构：

[1] ESCPE Lyon, CNRS, LCPP, Villeurbanne, France

[2] Univ Ottawa, Dept Chem Engn, Ottawa, ON, Canada

来源：

MACROMOLECULAR SYMPOSIA | 2004年 / 206卷

关键词：

bimodal molecular weight distribution; compartmentalisation; infrared spectroscopy; miniemulsion; polymerisation;

D O I：

10.1002/masy.200450209

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Infrared spectroscopy and differential scanning calorimetry were used to demonstrate that miniemulsions of relatively hydrophobic monomers are compartmentalised during the reaction. Experiments with blends of miniemulsions of different composition revealed that no mass transfer takes place between droplets of different composition in the same reactor. In addition, it was shown that it is possible to make high solids content, low viscosity latexes with bimodal particle size and molecular weight distributions because of this property.

引用

页码：107 / 119

页数：13

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