Structure and phase stability of lead-free antiferroelectric (Na0.96-xCa0.04Lix)(Nb0.96Zr0.04)O3 ceramics

被引:2
作者
Xu, Zunping [1 ]
Qiang, Hua [2 ]
Chen, Yi [1 ]
Liu, Gang [1 ]
机构
[1] Southwest Univ, Fac Mat & Energy, Chongqing 400715, Peoples R China
[2] Chongqing Coll Humanities Sci & Technol, Chongqing 401524, Peoples R China
关键词
GIANT PIEZOELECTRICITY; TEMPERATURE;
D O I
10.1007/s10854-018-0540-9
中图分类号
TM [电工技术]; TN [电子技术、通信技术];
学科分类号
0808 ; 0809 ;
摘要
(Na0.96-xCa0.04Lix)(Nb0.96Zr0.04)O-3 (CZNNL) ceramics with high density were successfully prepared by the solid-state reaction method. The effect of Li dopants on the structure, electrical properties and stability of antiferroelectricity has been investigated. Enhanced antiferroelectric superlattice peaks was observed for CZNNL (x0.01) using X-ray diffraction. Li substitution can effectively destabilize the antiferroelectric phase and correspondingly the ferroelectric phase can be enhanced. The field-induced polarization increase and the average grain size decrease with increasing Li concentration. The CZNNL (x=0.01) ceramics can preserve the double polarization hysteresis loops at room temperature and at 120 degrees C.
引用
收藏
页码:2647 / 2651
页数:5
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