A high thermoelectric figure of merit ZT > 1 in Ba heavily doped BiCuSeO oxyselenides

被引:334
作者
Li, Jing [1 ]
Sui, Jiehe [1 ]
Pei, Yanling [2 ]
Barreteau, Celine [3 ]
Berardan, David [3 ]
Dragoe, Nita [3 ]
Cai, Wei [1 ]
He, Jiaqing [4 ]
Zhao, Li-Dong [3 ]
机构
[1] Harbin Inst Technol, Sch Mat Sci & Engn, Natl Key Lab Precis Hot Proc Met, Harbin 150001, Peoples R China
[2] Beihang Univ, Sch Mat Sci & Engn, Beijing 100191, Peoples R China
[3] Univ Paris 11, LEMHE, ICMMO, CNRS UMR 8182, F-91405 Orsay, France
[4] Xi An Jiao Tong Univ, FIST, Xian 710054, Peoples R China
基金
中国国家自然科学基金;
关键词
NANOSTRUCTURED THERMOELECTRICS; THERMAL-CONDUCTIVITY; PERFORMANCE; ENHANCEMENT; OXIDE; PBS; EFFICIENCY; PBTE;
D O I
10.1039/c2ee22622g
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A high ZT value of similar to 1.1 at 923 K in the BiCuSeO system is achieved via heavily doping with Ba and refining grain sizes (200-400 nm), which is higher than any thermoelectric oxide. Excellent thermal and chemical stabilities up to 923 K and high thermoelectric performance confirm that the BiCuSeO system is promising for thermoelectric power generation applications.
引用
收藏
页码:8543 / 8547
页数:5
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