Ultra-high temperature oxidation of a hafnium carbide-based solid solution ceramic composite

被引:30
作者
Lipke, David W. [1 ]
Ushakov, Sergey V. [2 ,3 ]
Navrotsky, Alexandra [2 ,3 ]
Hoffman, Wesley P. [1 ]
机构
[1] AFRL RQRC, Air Force Res Lab, Edwards Afb, CA 93524 USA
[2] Univ Calif Davis, Peter A Rock Thermochem Lab, Davis, CA 95616 USA
[3] Univ Calif Davis, NEAT ORU, Davis, CA 95616 USA
关键词
Ceramic; High temperature corrosion; Oxidation; X-RAY-ABSORPTION; ZIRCONIA STABILIZATION; SILICON-CARBIDE; CARBON; DOPANTS; CHROMIUM; DIAGRAMS;
D O I
10.1016/j.corsci.2013.11.049
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Hafnium carbide-based solid solution ceramics with yttria additions were consolidated via hot pressing utilizing chromium carbide as a transient liquid sintering agent. Selected samples were oxidized at temperatures exceeding 2200 degrees C under high velocity airflow to determine their potential for service in ultrahigh temperature environments. Cross-sectional examination revealed a complex multi-layer scale comprising a highly porous exterior region, a dense multi-phase interior region, and an oxygen- and carbon-containing interlayer consisting of nanocrystalline graphite in an amorphous or nanocrystalline oxide matrix. Outward diffusion of mobile cations is speculated to play an important role in establishing the observed scale morphology. (C) 2013 Elsevier Ltd. All rights reserved.
引用
收藏
页码:402 / 407
页数:6
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