Stereospecific anionic polymerization of methyl bicyclobutane-1-carboxylate

被引：8
|
作者：
Kitayama, T [1 ]
Kawauchi, T
Chen, XP
Padias, AB
Hall, HK
机构：
[1] Osaka Univ, Grad Sch Engn Sci, Dept Chem, Osaka 5608531, Japan
[2] Univ Arizona, Dept Chem, Tucson, AZ 85721 USA
来源：
MACROMOLECULES | 2002年 / 35卷 / 09期
关键词：
D O I：
10.1021/ma012250l
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
The anionic polymerization of methyl bicyclobutane-1-carboxylate (MBCB) with combined initiators, tert-butyllithium (t-BuLi)/bis(2,6-di-tert-butylphenoxy)alkyl-aluminums was discussed. It was found that the solubility of poly (MBCB)s depended on their trans content. The analysis suggested that long trans sequence in the polymer were responsible for the solubility of stereoregular poly(MBCB)s.
引用
收藏
页码：3328 / 3330
页数：3
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