IR analysis of borate glasses containing three alkali oxides

被引：144

作者：

Balachander, L. ^{[1
]}

Ramadevudu, G. ^{[2
]}

Shareefuddin, Md. ^{[1
]}

Sayanna, R. ^{[3
]}

Venudhar, Y. C. ^{[3
]}

机构：

[1] Osmania Univ, Nizam Coll Autonomous, Dept Phys, Hyderabad 500001, Andhra Pradesh, India

[2] Vasavi Coll Engn, Dept Phys, Hyderabad 31, Andhra Pradesh, India

[3] Osmania Univ, Dept Phys, Hyderabad 500007, Andhra Pradesh, India

来源：

SCIENCEASIA | 2013年 / 39卷 / 03期

关键词：

glass formers; glass modifier; borate groups; non-bridging oxygen atoms; FT-IR; SHIELDING BEHAVIOR; INFRARED-SPECTRA; EPR;

D O I：

10.2306/scienceasia1513-1874.2013.39.278

中图分类号：

O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];

学科分类号：

07 ; 0710 ; 09 ;

摘要：

FTIR investigations on borate glasses containing three alkali oxides, xLi(2)O center dot xNa(2)O center dot K2O center dot (50-3x)PbO center dot 50B(2)O(3) (x = 8, 10, 12, 14, and 16 mol%), 10 Li2O center dot 10 Na2O center dot 10K(2)O center dot yPbO center dot (70-y)B2O3 (y = 25, 30, 35, 40, and 50 mol%), and x Li2O center dot xNa(2)O x K2O (50-3x) Bi2O3 center dot 50B(2)O(3) (x = 8, 10, 12, 14, and 16 mol%) are reported. The present glasses contain mainly BO3 and BO4 structural units. The presence of fingerprints of both BiO3 and BiO6 structural units in bismuth alkali borate glasses was confirmed. The presence of varied types like di, tetra, penta, and ortho borate groups are confirmed in the glass matrix. Glasses with low PbO content contained more BO3 units than BO4 units.

引用

页码：278 / 283

页数：6

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