A MOF- assisted phosphine free bifunctional iron complex for the hydrogenation of carbon dioxide, sodium bicarbonate and carbonate to formate

被引：33

作者：

Coufourier, Sebastien ^{[1
]}

Gaillard, Sylvain ^{[1
]}

Clet, Guillaume ^{[2
]}

Serre, Christian ^{[3
]}

Daturi, Marco ^{[2
]}

Renaud, Jean-Luc ^{[1
]}

机构：

[1] Normandie Univ, LCMT, ENSICAEN, UNICAEN,CNRS, 6 Blvd Marechal Juin, F-14000 Caen, France

[2] Normandie Univ, ENSICAEN, UNICAEN, CNRS,LCS, F-14000 Caen, France

[3] PSL Res Univ, Inst Mat Poreux Paris, UMR CNRS 8004, Ecole Normale Super,Ecole Super Phys & Chim Ind P, F-75005 Paris, France

来源：

CHEMICAL COMMUNICATIONS | 2019年 / 55卷 / 34期

关键词：

METAL-ORGANIC FRAMEWORKS; CATALYZED CO2 HYDROGENATION; FORMIC-ACID; REDUCTION; METHANOL; METHYLATION; ALKYLATION; REACTIVITY; CONVERSION; MIL-53;

D O I：

10.1039/c8cc09771b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The hydrogenation of carbon dioxide into formic acid (FA) with Earth-abundant metals is a vibrant research area because FA is an attractive molecule for hydrogen storage. We report a cyclopentadienyl iron tricarbonyl complex that provides up to 3000 turnover number for carbon dioxide hydrogenation when combined with a catalytic amount of the chromium dicarboxylate MOF MIL-53(Cr). To date, this is the highest turnover number reported in the presence of a phosphine-free iron complex.

引用

页码：4977 / 4980

页数：4

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