A MOF- assisted phosphine free bifunctional iron complex for the hydrogenation of carbon dioxide, sodium bicarbonate and carbonate to formate

被引：33
作者：
Coufourier, Sebastien [1 ]
Gaillard, Sylvain [1 ]
Clet, Guillaume [2 ]
Serre, Christian [3 ]
Daturi, Marco [2 ]
Renaud, Jean-Luc [1 ]
机构：
[1] Normandie Univ, LCMT, ENSICAEN, UNICAEN,CNRS, 6 Blvd Marechal Juin, F-14000 Caen, France
[2] Normandie Univ, ENSICAEN, UNICAEN, CNRS,LCS, F-14000 Caen, France
[3] PSL Res Univ, Inst Mat Poreux Paris, UMR CNRS 8004, Ecole Normale Super,Ecole Super Phys & Chim Ind P, F-75005 Paris, France
来源：
CHEMICAL COMMUNICATIONS | 2019年 / 55卷 / 34期
关键词：
METAL-ORGANIC FRAMEWORKS; CATALYZED CO2 HYDROGENATION; FORMIC-ACID; REDUCTION; METHANOL; METHYLATION; ALKYLATION; REACTIVITY; CONVERSION; MIL-53;
D O I：
10.1039/c8cc09771b
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The hydrogenation of carbon dioxide into formic acid (FA) with Earth-abundant metals is a vibrant research area because FA is an attractive molecule for hydrogen storage. We report a cyclopentadienyl iron tricarbonyl complex that provides up to 3000 turnover number for carbon dioxide hydrogenation when combined with a catalytic amount of the chromium dicarboxylate MOF MIL-53(Cr). To date, this is the highest turnover number reported in the presence of a phosphine-free iron complex.
引用
收藏
页码：4977 / 4980
页数：4
相关论文
共 59 条
[1]   Challenges in the Greener Production of Formates/Formic Acid, Methanol, and DME by Heterogeneously Catalyzed CO2 Hydrogenation Processes [J].
Alvarez, Andrea ;
Bansode, Atul ;
Urakawa, Atsushi ;
Bavykina, Anastasiya V. ;
Wezendonk, Tim A. ;
Makkee, Michiel ;
Gascon, Jorge ;
Kapteijn, Freek .
CHEMICAL REVIEWS, 2017, 117 (14) :9804-9838
[2]   Sustainable Conversion of Carbon Dioxide: An Integrated Review of Catalysis and Life Cycle Assessment [J].
Artz, Jens ;
Mueller, Thomas E. ;
Thenert, Katharina ;
Kleinekorte, Johanna ;
Meys, Raoul ;
Sternberg, Andre ;
Bardow, Andre ;
Leitner, Walter .
CHEMICAL REVIEWS, 2018, 118 (02) :434-504
[3]   Cp*Co(III) Catalysts with Proton-Responsive Ligands for Carbon Dioxide Hydrogenation in Aqueous Media [J].
Badiei, Yosra M. ;
Wang, Wan-Hui ;
Hull, Jonathan F. ;
Szalda, David J. ;
Muckerman, James T. ;
Himeda, Yuichiro ;
Fujita, Etsuko .
INORGANIC CHEMISTRY, 2013, 52 (21) :12576-12586
[4]   Reversible Hydrogenation of Carbon Dioxide to Formic Acid and Methanol: Lewis Acid Enhancement of Base Metal Catalysts [J].
Bernskoetter, Wesley H. ;
Hazari, Nilay .
ACCOUNTS OF CHEMICAL RESEARCH, 2017, 50 (04) :1049-1058
[5]   Carbon dioxide hydrogenation catalysed by well-defined Mn(I) PNP pincer hydride complexes [J].
Bertini, Federica ;
Glatz, Mathias ;
Gorgas, Nikolaus ;
Stoeger, Berthold ;
Peruzzini, Maurizio ;
Veiros, Luis F. ;
Kirchner, Karl ;
Gonsalvi, Luca .
CHEMICAL SCIENCE, 2017, 8 (07) :5024-5029
[6]   Efficient and Mild Carbon Dioxide Hydrogenation to Formate Catalyzed by Fe(II) Hydrido Carbonyl Complexes Bearing 2,6-(Diaminopyridyl)diphosphine Pincer Ligands [J].
Bertini, Federica ;
Gorgas, Nikolaus ;
Stoeger, Berthold ;
Peruzzini, Maurizio ;
Veiros, Luis F. ;
Kirchner, Karl ;
Gonsalvi, Luca .
ACS CATALYSIS, 2016, 6 (05) :2889-2893
[7]   Iron(II) Complexes of the Linear rac-Tetraphos-1 Ligand as Efficient Homogeneous Catalysts for Sodium Bicarbonate Hydrogenation and Formic Acid Dehydrogenation [J].
Bertini, Federica ;
Mellone, Irene ;
Ienco, Andrea ;
Peruzzini, Maurizio ;
Gonsalvi, Luca .
ACS CATALYSIS, 2015, 5 (02) :1254-1265
[8]  
Bhanage B., 2014, TRANSFORMATION UTILI
[9]   Metal-organic frameworks for the removal of toxic industrial chemicals and chemical warfare agents [J].
Bobbitt, N. Scott ;
Mendonca, Matthew L. ;
Howarth, Ashlee J. ;
Islamoglu, Timur ;
Hupp, Joseph T. ;
Farha, Omar K. ;
Snurr, Randall Q. .
CHEMICAL SOCIETY REVIEWS, 2017, 46 (11) :3357-3385
[10]   Hydrogenation of CO2 in Water Using a Bis(diphosphine) Ni-H Complex [J].
Burgess, Samantha A. ;
Kendall, Alexander J. ;
Tyler, David R. ;
Linehan, John C. ;
Appel, Aaron M. .
ACS CATALYSIS, 2017, 7 (04) :3089-3096
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