Conversion of Americia to Anhydrous Trivalent Americium Halides

被引：19

作者：

Galley, Shane S. ^{[1
]}

Sperling, Joseph M. ^{[2
]}

Windorff, Cory J. ^{[2
]}

Zeller, Matthias ^{[1
]}

Albrecht-Schmitt, Thomas E. ^{[2
]}

Bart, Suzanne C. ^{[1
]}

机构：

[1] Purdue Univ, Dept Chem, HC Brown Lab, W Lafayette, IN 47907 USA

[2] Florida State Univ, Dept Chem & Biochem, Tallahassee, FL 32306 USA

来源：

ORGANOMETALLICS | 2019年 / 38卷 / 03期

关键词：

CHEMISTRY; COMPLEXES; URANIUM; NP; TH;

D O I：

10.1021/acs.organomet.8b00840

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Anhydrous americium(III) starting materials were prepared from americia (AmO2) using inexpensive, commercially available reagents and mild reaction conditions. [AmCl(mu-Cl)(2)(THF)(2)](n) (1-Am) and AmBr3(THF)(4)(2-Am) were isolated and characterized by electronic absorption spectroscopy and X-ray diffraction. These new starting materials are soluble in organic solvents, making them useful synthons for nonaqueous organometallic americium chemistry.

引用

页码：606 / 609

页数：4

共 27 条

[1] A CONVENIENT ENTRY INTO TRIVALENT ACTINIDE CHEMISTRY - SYNTHESIS AND CHARACTERIZATION OF ANI3(THF)4 AND AN[N(SIME3)2]3 (AN=U, NP, PU)
AVENS, LR
BOTT, SG
CLARK, DL
SATTELBERGER, AP
WATKIN, JG
ZWICK, BD
[J]. INORGANIC CHEMISTRY, 1994, 33 (10) : 2248 - 2256
[2] TETRAKIS(CYCLOPENTADIENYL)NEPTUNIUM(4)
BAUMGART.F
FISCHER, EO
KANELLAK.B
LAUBEREA.P
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1968, 7 (08) : 634 - +
[3] Bohlander R., 1986, ORGANOMETALLIC CHEM
[4] THE BONDING IN TRIS(ETA-5-CYCLOPENTADIENYL) ACTINIDE COMPLEXES .4. ELECTRONIC STRUCTURAL EFFECTS IN ANCL3 AND (ETA-5-C5H5)3 TH, (ETA-5-C5H5)3CF COMPLEXES
BURSTEN, BE
RHODES, LF
STRITTMATTER, RJ
[J]. JOURNAL OF THE LESS-COMMON METALS, 1989, 149 (1-2): : 207 - 211
[5] Emergence of californium as the second transitional element in the actinide series
Cary, Samantha K.
Vasiliu, Monica
Baumbach, Ryan E.
Stritzinger, Jared T.
Green, Thomas D.
Diefenbach, Kariem
Cross, Justin N.
Knappenberger, Kenneth L.
Liu, Guokui
Silver, Mark A.
DePrince, A. Eugene
Polinski, Matthew J.
Van Cleve, Shelley M.
House, Jane H.
Kikugawa, Naoki
Gallagher, Andrew
Arico, Alexandra A.
Dixon, David A.
Albrecht-Schmitt, Thomas E.
[J]. NATURE COMMUNICATIONS, 2015, 6
[6] Covalency in Americium(III) Hexachloride
Cross, Justin N.
Su, Jing
Batista, Enrique R.
Cary, Samantha K.
Evans, William J.
Kozimor, Stosh A.
Mocko, Veronika
Scott, Brian L.
Stein, Benjamin W.
Windorff, Cory J.
Yang, Ping
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2017, 139 (25) : 8667 - 8677
[7] Preparation and X-ray crystal structures of tetrahydrofuran-complexed rare earth chlorides - a structurally rich series
Deacon, GB
Feng, T
Junk, PC
Skelton, BW
Sobolev, AN
White, AH
[J]. AUSTRALIAN JOURNAL OF CHEMISTRY, 1998, 51 (01) : 75 - 89
[8] Bis(cyclooctatetraenyl)neptunium(IV)
DeRidder, DJA
Rebizant, J
Apostolidis, C
Kanellakopulos, B
Dornberger, E
[J]. ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1996, 52 : 597 - 600
[9] Reduction chemistry of neptunium cyclopentadienide complexes: from structure to understanding
Dutkiewicz, Michal S.
Apostolidis, Christos
Walter, Olaf
Arnold, Polly L.
[J]. CHEMICAL SCIENCE, 2017, 8 (04) : 2553 - 2561
[10] STRUCTURAL DIVERSITY IN SOLVATED LANTHANIDE HALIDE-COMPLEXES
EVANS, WJ
SHREEVE, JL
ZILLER, JW
DOEDENS, RJ
[J]. INORGANIC CHEMISTRY, 1995, 34 (03) : 576 - 585

← 1 2 3 →