Direct decomposition technique for NO in O2-N2 mixture using barrier discharge and Cu zeolite

被引:10
作者
Goto, N [1 ]
Kudo, S [1 ]
Motoyama, H [1 ]
Ohyama, S [1 ]
机构
[1] Cent Res Inst Elect Power Ind, Komae, Tokyo 2018511, Japan
来源
JAPANESE JOURNAL OF APPLIED PHYSICS PART 2-LETTERS & EXPRESS LETTERS | 2002年 / 41卷 / 1AB期
关键词
NOx; barrier discharge; decomposition of NO; environmental application;
D O I
10.1143/JJAP.41.L64
中图分类号
O59 [应用物理学];
学科分类号
摘要
A new method of increasing the efficiency of NO direct decomposition in an O-2-N-2 mixture using barrier discharge and copper ion-exchanged ZSM-5 zeolites (Cu-ZSM-5) is proposed. After NO is adsorbed on Cu-ZSM-5 in a flow with 200 ppm NO, 9% O-2, and N-2, the Cu-ZSM-5 with adsorbed NO is treated with a barrier-discharge plasma in N-2. The reaction N + NO --> N-2 + O increases because of the high concentration of NO on the surface of Cu-ZSM-5. As a result of the discharge, NO decomposition efficiency is about 37%, and NO2 and N2O generation efficiencies are only 5% and 4%, respectively, These results show that this technique enables low oxidation and high direct decomposition of NO in an O-2-N-2 mixture.
引用
收藏
页码:L64 / L66
页数:3
相关论文
共 11 条
[11]  
Vercammen K. L. L., 1997, J. Adv. Oxid. Technol, V2, P312