Radical addition reaction of 2-benzoyloxypentafluoropropene onto cycloalkanes

被引：15

作者：

Narita, T

Hagiwara, T

Hamana, H

Kitamura, K

Inagaki, Y

Yoshida, Y

机构：

[1] Saitama Inst Technol, Dept Appl Chem, Okabe, Saitama 3690293, Japan

[2] Toyo Univ, Dept Appl Chem, Kawagoe, Saitama 3508585, Japan

来源：

JOURNAL OF FLUORINE CHEMISTRY | 1999年 / 97卷 / 1-2期

关键词：

2-benzoyloxypentafluoropropene; radical addition; cyclopentane; cyclohexane; cycloheptane; perfluoroisopropenyl cyclohexanecarboxylate;

D O I：

10.1016/S0022-1139(99)00072-X

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The radical addition reactions of 2-benzoyloxypentafluoropropene [CF2=C(CF3)OCOC6H5] (BPFP), an F-enol ester, with cyclopentane, cyclohexane and cycloheptane in the presence of benzoyl peroxide are shown to afford the 1:1 addition products of BPFP with the cycloalkanes. The structures of the reaction products were confirmed by the mass spectra and H-1, C-13 and F-19 NMR measurements. Similar additions of perfluoroisopropenyl cyclohexanecarboxylate with cycloalkanes were also investigated. (C) 1999 Elsevier Science S.A. All rights reserved.

引用

页码：263 / 265

页数：3

共 8 条

[1] FREE-RADICAL CHEMISTRY 2 ADDITIONS OF DIMETHYLETHER TO F-CYCLOALKENES [J].