Plugging a Molecular Wire into Photosystem I: Reconstitution of the Photoelectric Conversion System on a Gold Electrode

被引：99

作者：

Terasaki, Nao ^{[1
]}

Yamamoto, Noritaka ^{[1
]}

Hiraga, Takashi ^{[1
]}

Yamanoi, Yoshinori ^{[2
]}

Yonezawa, Tetsu ^{[2
]}

Nishihara, Hiroshi ^{[2
]}

Ohmori, Tsutomu ^{[3
]}

Sakai, Makoto ^{[3
]}

Fujii, Masaaki ^{[3
]}

Tohri, Akihiko ^{[4
]}

Iwai, Masako ^{[4
]}

Inoue, Yasunori ^{[4
]}

Yoneyama, Satoshi ^{[5
]}

Minakata, Makoto ^{[5
]}

Enami, Isao ^{[6
]}

机构：

[1] Natl Inst Adv Ind Sci & Technol, Saga 8410052, Japan

[2] Univ Tokyo, Dept Chem, Bunkyo Ku, Tokyo 1138654, Japan

[3] Tokyo Inst Technol, Chem Resources Lab, Midori Ku, Yokohama, Kanagawa 2268503, Japan

[4] Tokyo Univ Sci, Dept Appl Biol Sci, Chiba 2788510, Japan

[5] Shizuoka Univ, Elect Res Inst, Naka Ku, Shizuoka 4328011, Japan

[6] Tokyo Univ Sci, Dept Biol, Shinjuku Ku, Tokyo 1628601, Japan

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2009年 / 48卷 / 09期

关键词：

biocomponents; electron transfer; molecular electronics; photocurrent; photosynthesis; PHOTOSYNTHETIC REACTION CENTERS; LANGMUIR-BLODGETT-FILMS; RHODOPSEUDOMONAS-VIRIDIS; REDOX COFACTORS; NANOPARTICLE; PROTEIN;

D O I：

10.1002/anie.200805748

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Figure Presented) Plug and play: Photoinduced electron transfer occurs from photoexcited P700 in photosystem I (PSI) to a gold surface (see picture). A novel is used, in which an artificial molecular wire, which is assembled on the gold surface, was plugged into PSI by reconstitution. Analysis of the kinetics proved both the output of electrons from PSI and the effectiveness of the molecular wire. © 2009 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：1585 / 1587

页数：3

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