Factors influencing the synthesis and the post-modification of PEGylated pentafluorophenyl acrylate containing copolymers

被引：32

作者：

Beija, Mariana ^{[1
]}

Li, Yang ^{[1
]}

Lowe, Andrew B. ^{[1
]}

Davis, Thomas P. ^{[1
]}

Boyer, Cyrille ^{[1
]}

机构：

[1] Univ New S Wales, Sch Chem Engn, Ctr Adv Macromol Design, Sydney, NSW 2052, Australia

来源：

EUROPEAN POLYMER JOURNAL | 2013年 / 49卷 / 10期

基金：

澳大利亚研究理事会;

关键词：

RAFT polymerization; Functional polymer; Copolymers; Activate ester; Postmodification; Thermoresponsive polymers; LIVING RADICAL POLYMERIZATION; FRAGMENTATION CHAIN TRANSFER; RAFT POLYMERIZATION; DIBLOCK COPOLYMERS; ACTIVE ESTER; PRECURSOR POLYMERS; CLICK CHEMISTRY; STAR POLYMERS; PROTEIN; NANOPARTICLES;

D O I：

10.1016/j.eurpolymj.2013.05.003

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Copolymerization reactions involving oligoethylene glycol acrylate (OEGA) or diethylene glycol acrylate (DEGA) with pentafluorophenyl acrylate (PFPA) have been performed by reversible addition fragmentation transfer (RAFT) polymerization. The effect of the reaction conditions on the nucleophilic acyl substitution reactions of PFPA was studied using a model amine (furfuryl amine). The resulting PEG/PFP functional copolymers were then used as scaffolds to produce a library of polymers by reaction with a range of amines. (C) 2013 Elsevier Ltd. All rights reserved.

引用

页码：3060 / 3071

页数：12

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