Two pseudopolymorphs derived from alkaline earth metals and the pseudopeptidic ligand trimesoyl-tris-glycine

被引：5

作者：

Dokorou, Vassiliki N. ^{[1
,2
]}

Powell, Annie K. ^{[1
]}

Kostakis, George E. ^{[1
]}

机构：

[1] Karlsruhe Inst Technol, Inst Nanotechnol, D-76344 Eggenstein Leopoldshafen, Germany

[2] Univ Ioannina, Dept Chem, Xray Unit, GR-45110 Ioannina, Greece

来源：

POLYHEDRON | 2013年 / 52卷

关键词：

Coordination polymers; Topology; Catenation; Pseudopolymorphs; ORGANIC RING INTERACTIONS; COORDINATION POLYMERS; FRAMEWORKS; CHEMISTRY; NETWORKS; ACID; N,N',N''-TRIS(CARBOXYMETHYL)-1,3,5-BENZENETRICARBOXAMIDE; POLYCATENATION; TOPOLOGY; WATER;

D O I：

10.1016/j.poly.2012.08.032

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of Ca(NO3)(2)center dot 3H(2)O and Sr(NO3)(2) with trimesoyl-tris-glycine (H3L) leads to a two dimensional (2D) [Ca-2(HL)(2)(mu-H2O)(H2O)(5)]center dot 3H(2)O (1) and a three dimensional (3D) [Sr-2(HL)(2)(H2O)(7)]center dot H2P (2) coordination polymer, respectively, illustrating the substantial influence of the ionic radii of the alkaline earth metals in determining the motif of the final product. (C) 2012 Elsevier Ltd. All rights reserved.

引用

页码：538 / 544

页数：7

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