Low-temperature synthesis of ammonia borane using diborane and ammonia

被引：12

作者：

Choi, Ho Yun ^{[1
]}

Park, Sung Jin ^{[1
]}

Seo, Dongho ^{[1
]}

Baek, Jong-min ^{[1
]}

Song, Han Dock ^{[1
]}

Jung, Sung Jin ^{[1
]}

Lee, Kun Jong ^{[1
]}

Kim, Young Lae ^{[1
]}

机构：

[1] Wonik Mat Co Ltd, Res & Dev Grp, Ochang Eup 363885, Cheongwon, South Korea

来源：

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY | 2015年 / 40卷 / 35期

关键词：

Ammonia borane; Diborane; Ammonia; Synthesis; Hydrogen; HYDROGEN GENERATION; STORAGE; DEHYDROGENATION; CATALYST; NMR;

D O I：

10.1016/j.ijhydene.2015.03.100

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Ammonia borane (NH3BH3), as a source material for energy generation and hydrogen storage, has attracted growing interest due to its high hydrogen content. We have investigated the synthesis of ammonia borane from diborane (B2H6) and ammonia (NH3) utilizing a low-temperature process. From our results, a maximum synthetic yield of 92.2% was obtained, for an ammonia borane complex of 0.35 M. The diammoniate diborane (DADB) was detected in about 5-10 mol% within the solid ammonia borane by solid-state B-11-NMR analysis. The synthesized solid ammonia borane products were studied to characterize hydrogen release upon thermal dehydrogenation. Copyright (C) 2015, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.

引用

页码：11779 / 11784

页数：6

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