Inclusion by a substituted binaphthyl host: structures and kinetics of desolvation

被引：2

作者：

Nassimbeni, Luigi R. ^{[1
]}

Su, Hong ^{[1
]}

Davies, Kate ^{[1
]}

Weber, Edwin ^{[2
]}

机构：

[1] Univ Cape Town, Dept Chem, ZA-7701 Cape Town, South Africa

[2] Tech Univ Bergakad Freiberg, Inst Organ Chem, D-09596 Freiberg, Germany

来源：

SUPRAMOLECULAR CHEMISTRY | 2013年 / 25卷 / 05期

关键词：

binaphthyl host; dehydration product; X-ray crystal structure; conformational analysis; kinetics; COMPLEXATION; CLATHRATE; CH2CL2;

D O I：

10.1080/10610278.2013.775444

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The host compound 2,2-bis(hydroxydiphenylmethyl)-1,1-binaphthyl displays a remarkably constant conformation, which is governed chiefly by an intramolecular OH...O hydrogen bond. Its inclusion compound with chloroform has been characterised and the dehydration product affords the corresponding oxepine with significantly different conformation.

引用

页码：310 / 314

页数：5

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