Synthesis, Molecular and Crystal Structure of Ethyl 5-Cyano-2-(Dicyanomethyl)-2-Methyl-4-Oxo-6-Phenyl-3-Azabicyclo[3.1.0]Hexane-1-Carboxylate

被引：6

作者：

Ismiyev, A. I. ^{[1
]}

Potekhin, K. A. ^{[2
]}

Maleev, A. V. ^{[2
]}

Askerov, R. K. ^{[1
]}

Maharramov, A. M. ^{[1
]}

机构：

[1] Baku State Univ, Baku, Azerbaijan

[2] Vladimir State Univ, Vladimir, Russia

来源：

JOURNAL OF STRUCTURAL CHEMISTRY | 2019年 / 60卷 / 03期

关键词：

multicomponent cascade condensation; malonodinitrile; 3-azabicyclo[3; 1; 0]hexane; atom-atom potentials; molecular agglomerates; molecular salts; hydrogen bond; ONE-POT SYNTHESIS; MALONATE; MALONONITRILE; ALDEHYDE;

D O I：

10.1134/S0022476619030181

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

As a result of triple condensation of malonodinitrile with benzaldehyde and ethyl 2-chloro-3-oxobutanoate a compound with 3-azabicyclo[3.1.0]hexane framework is formed whose crystal structure is determined by X-ray crystallography. In the crystal structure a layered character of the molecular packing is found. Molecules are linked in the layer by H bonds of N-H...O=C and C-H...O=C types and also a large number of atom-atom contacts whose energy corresponds to potential wells.

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页码：485 / 493

页数：9

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