Thermolabile Noble Metal Precursors: (NO)[Au(NO3)4], (NO)2[Pd(NO3)4], and (NO)2[Pt(NO3)6]

被引：29

作者：

Wickleder, Mathias S. ^{[1
]}

Gerlach, Frauke ^{[1
]}

Gagelmann, Steffen ^{[1
]}

Bruns, Joern ^{[1
]}

Fenske, Mandus ^{[1
]}

Al-Shamery, Katharina ^{[1
]}

机构：

[1] Carl von Ossietzky Univ Oldenburg, Inst Pure & Appl Chem, D-26129 Oldenburg, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2012年 / 51卷 / 09期

关键词：

analytical methods; nitrates; noble metals; photoelectron spectroscopy; CHEMICAL VAPOR-DEPOSITION; GOLD; DECOMPOSITION; CATALYSTS; GAS;

D O I：

10.1002/anie.201106107

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Oxidizing noble metals: Pure N2O5 can oxidize elemental gold and palladium. The complex nitrates obtained by these reactions, (NO)[Au(NO3)4], (NO)2[Pd(NO3) 4], and also the first nitrate of tetravalent platinum, (NO) 2[Pt(NO3)6] (see picture for the anion: Pt-gray, N-green, O-blue), have the potential to act as precursors owing to their high thermolability. The thermal decomposition of (NO)[Au(NO 3)4] was elucidated in detail by several methods. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：2199 / 2203

页数：5

共 26 条

[1] TETRANITRATOAURATES(III) - PREPARATION, SPECTRA, AND PROPERTIES [J].

ADDISON, CC ;

BROWNLEE, GS ;

LOGAN, N .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1972, (14) :1440-&

[2] DINITROGEN TETROXIDE, NITRIC-ACID, AND THEIR MIXTURES AS MEDIA FOR INORGANIC REACTIONS [J].

ADDISON, CC .

CHEMICAL REVIEWS, 1980, 80 (01) :21-39

[3]

[Anonymous], 2007, ANGEW CHEM

[4] PROJECTION PRINTING OF GOLD MICROPATTERNS BY PHOTOCHEMICAL DECOMPOSITION [J].

BAUM, TH ;

MARINERO, EE ;

JONES, CR .

APPLIED PHYSICS LETTERS, 1986, 49 (18) :1213-1215

[5] LASER CHEMICAL VAPOR-DEPOSITION OF GOLD [J].

BAUM, TH ;

JONES, CR .

APPLIED PHYSICS LETTERS, 1985, 47 (05) :538-540

[6] LASER CHEMICAL VAPOR-DEPOSITION OF GOLD .2. [J].

BAUM, TH ;

JONES, CR .

JOURNAL OF VACUUM SCIENCE & TECHNOLOGY B, 1986, 4 (05) :1187-1191

[7] Catalysis by gold [J].

Bond, GC ;

Thompson, DT .

CATALYSIS REVIEWS-SCIENCE AND ENGINEERING, 1999, 41 (3-4) :319-388

[8]

Brauer G., 1975, HDB PRAPARATIVEN ANO, P1719

[9]

Brauer G., 1975, HDB PRAPARATIVEN ANO, P473

[10] ELECTRON-BEAM FABRICATION OF 80-A METAL STRUCTURES [J].

BROERS, AN ;

MOLZEN, WW ;

CUOMO, JJ ;

WITTELS, ND .

APPLIED PHYSICS LETTERS, 1976, 29 (09) :596-598

← 1 2 3 →