Optical, electrical, and thermochromic properties of polyazothiophene Langmuir-Blodgett films

被引:10
作者
Goncalves, Vanessa C. [1 ]
Ferreira, Marystela [2 ]
Olivati, Clarissa A. [3 ]
Cardoso, Marcos R. [1 ]
Mendonca, Cleber R. [1 ]
Balogh, Debora T. [1 ]
机构
[1] Univ Sao Paulo, Inst Fis Sao Carlos, BR-13560970 Sao Carlos, Brazil
[2] Univ Fed Sao Carlos, BR-18043970 Sao Paulo, Brazil
[3] UNESP, Depto Fis IGCE, BR-13500230 Rio Claro, SP, Brazil
基金
巴西圣保罗研究基金会;
关键词
Langmuir-Blodgett; polythiophenes; azobenzene;
D O I
10.1007/s00396-008-1909-8
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The conductivity and luminescence of conjugated polymers may be combined with the photoisomerization capability of azobenzene materials to achieve unique properties for a variety of applications, particularly if conjugated polymers with azobenzene side chains are processed as nanostructured films. In this study, we report on Langmuir-Blodgett (LB) films of a polythiophene-bearing azobenzene moieties, which displayed photoluminescence, thermochromism, electroactivity, and photoinduced birefringence. The latter three properties were enhanced in the LB films, as compared to spin-coated films of the polyazothiophene, and this has been attributed to differences in film morphology that could be probed with atomic force microscopy.
引用
收藏
页码:1395 / 1401
页数:7
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