Modeling of an equivalent circuit for dye-sensitized solar cells

被引:557
作者
Han, LY [1 ]
Koide, N [1 ]
Chiba, Y [1 ]
Mitate, T [1 ]
机构
[1] Sharp Co Ltd, Ecol Technol Dev Ctr, Shinjo, Nara 6392198, Japan
关键词
D O I
10.1063/1.1690495
中图分类号
O59 [应用物理学];
学科分类号
摘要
Internal resistance in a dye-sensitized solar cell (DSC) was investigated using electrochemical impedance spectroscopy measurements. Four resistance. elements were observed in the impedance spectra, and-their dependencies on the applied bias voltage were characterized. It is found that the resistance element related to charge transport at the Tio(2)/dye/electrolyte interface displays behavior like that of a diode, and the series resistance elements largely correspond to the sum of the other resistance elements. An equivalent circuit for DSCs is proposed based on these results. (C) 2004 American Institute of Physics.
引用
收藏
页码:2433 / 2435
页数:3
相关论文
共 12 条
[1]   Sensitization of TiO2 by polypyridine dyes -: Role of the electron donor [J].
Bernard, MC ;
Cachet, H ;
Falaras, P ;
Hugot-Le Goff, A ;
Kalbac, M ;
Lukes, I ;
Oanh, NT ;
Stergiopoulos, T ;
Arabatzis, I .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2003, 150 (03) :E155-E164
[2]  
Gabrieli C., 1995, PHYSICAL ELECTROCHEM, P243
[3]  
GRAETZEL M, 1991, COMMENTS INORG CHEM, V12, P93
[4]   Highly efficient photon-to-electron conversion with mercurochrome-sensitized nanoporous oxide semiconductor solar cells [J].
Hara, K ;
Horiguchi, T ;
Kinoshita, T ;
Sayama, K ;
Sugihara, H ;
Arakawa, H .
SOLAR ENERGY MATERIALS AND SOLAR CELLS, 2000, 64 (02) :115-134
[5]   Diffusion in the electrolyte and charge-transfer reaction at the platinum electrode in dye-sensitized solar cells [J].
Hauch, A ;
Georg, A .
ELECTROCHIMICA ACTA, 2001, 46 (22) :3457-3466
[6]   Enhanced stability of photocurrent-voltage curves in Ru(II)-dye-sensitized nanocrystalline TiO2 electrodes with carboxylic acids [J].
Kang, TS ;
Chun, KH ;
Hong, JS ;
Moon, SH ;
Kim, KJ .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2000, 147 (08) :3049-3053
[7]   Modeling and interpretation of electrical impedance spectra of dye solar cells operated under open-circuit conditions [J].
Kern, R ;
Sastrawan, R ;
Ferber, J ;
Stangl, R ;
Luther, J .
ELECTROCHIMICA ACTA, 2002, 47 (26) :4213-4225
[8]   CONVERSION OF LIGHT TO ELECTRICITY BY CIS-X2BIS(2,2'-BIPYRIDYL-4,4'-DICARBOXYLATE)RUTHENIUM(II) CHARGE-TRANSFER SENSITIZERS (X = CL-, BR-, I-, CN-, AND SCN-) ON NANOCRYSTALLINE TIO2 ELECTRODES [J].
NAZEERUDDIN, MK ;
KAY, A ;
RODICIO, I ;
HUMPHRYBAKER, R ;
MULLER, E ;
LISKA, P ;
VLACHOPOULOS, N ;
GRATZEL, M .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1993, 115 (14) :6382-6390
[9]  
NISHIOKA K, 2001, P 17 EUR PHOT SOL EN, P1698
[10]  
Sze S.M., 2013, SEMICONDUCTOR DEVICE