Self-Organization of Gold Chloride Molecules on Au(111) Surface

被引：17

作者：

Andryushechkin, Boris V. ^{[1
]}

Cherkez, Vladimir V. ^{[1
,2
]}

Gladchenko, Eugeny V. ^{[1
]}

Pavlova, Tatiana V. ^{[1
]}

Zhidomirov, Georgy M. ^{[1
,3
]}

Kierren, Bertrand ^{[2
]}

Didiot, Clement ^{[2
]}

Fagot-Revurat, Yannick ^{[2
]}

Malterre, Daniel ^{[2
]}

Eltsov, Konstantin N. ^{[1
,4
]}

机构：

[1] Russian Acad Sci, AM Prokhorov Gen Phys Inst, Int Joint Lab IMTAS, Moscow 119991, Russia

[2] Univ Lorraine, Inst Jean Lamour, Int Joint Lab IMTAS, UMR CNRS 7198, F-54506 Vandoeuvre Les Nancy, France

[3] Russian Acad Sci, Siberian Branch, GK Boreskov Inst Catalysis, Novosibirsk 630090, Russia

[4] State Univ, Moscow Inst Phys & Technol, Dolgoprudnyi 141700, Moskovskaya Obl, Russia

来源：

JOURNAL OF PHYSICAL CHEMISTRY C | 2013年 / 117卷 / 47期

关键词：

TOTAL-ENERGY CALCULATIONS; WAVE BASIS-SET; INITIO; OXIDATION; CHEMISTRY; DYNAMICS; STYRENE; METALS;

D O I：

10.1021/jp409258z

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Adsorption of molecular chlorine on Au(111) has been studied with a low-temperature (5 K) scanning tunneling microscope in combination with density functional theory calculations. The formation of AuCl2 quasi-molecules was detected at chlorine coverage exceeding 0.33 ML. The self-organization of the AuCl2 species into the ordered "honeycomb" structure was clearly demonstrated for coverages close to saturation.

引用

页码：24948 / 24954

页数：7

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