Investigation of MnO2/CuO/rGO ternary nanocomposite as electrode material for high-performance supercapacitor

被引:37
作者
Jennifer, P. Joselene Suzan [1 ,2 ]
Muthupandi, S. [1 ]
Niranjana, S. R. [3 ]
Ruban, M. Joe Raja [1 ,2 ]
Madhavan, J. [1 ]
Prathap, S. [1 ]
Raj, M. Victor Antony [1 ,2 ]
机构
[1] Univ Madras, Dept Phys, Loyola Coll, Chennai 600034, Tamil Nadu, India
[2] Loyola Coll, Loyola Inst Frontier Energy, Chennai 600034, India
[3] Panimalar Engn Coll, Dept Phys, Chennai City Campus, Chennai 600029, India
关键词
Nanoparticles; Electrical properties; Electrodes; Electrochemical; ELECTROCHEMICAL SUPERCAPACITOR; HYBRID; MN; CU;
D O I
10.1016/j.inoche.2022.110218
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Here, utilising easily available precursor, we technologically advanced a modest and affordable way to form carbon-grounded material interlaced with metal oxides to form a controlled structure. As a hard substrate, interconnect microstructures were built via the in-situ creation of rGO/MnO2-rod/CuO-sphere (MCR) nanoparticles, which could significantly enhance capacitive active sites and encourage electrolyte transport during the electrochemical process. The modified sample showed excellent cycling stability with capacitance retention of 83.74 % after 5000 cycles at 10 A/g and a high specific capacitance of 658.97 F/g at a current density of 1 A/g. Additionally, at an energy density of 118.61 Wh/kg, the supercapacitor made of MCR electrodes demonstrated a power density of 1.5 kW/kg. This research presents a viable method for creating supercapacitor electrodes with great performance.
引用
收藏
页数:10
相关论文
共 36 条
[1]   Fast and fully-scalable synthesis of reduced graphene oxide [J].
Abdolhosseinzadeh, Sina ;
Asgharzadeh, Hamed ;
Kim, Hyoung Seop .
SCIENTIFIC REPORTS, 2015, 5
[2]   Synthesis, Characterization, and Antimicrobial Activity of Copper Oxide Nanoparticles [J].
Ahamed, Maqusood ;
Alhadlaq, Hisham A. ;
Khan, M. A. Majeed ;
Karuppiah, Ponmurugan ;
Al-Dhabi, Naif A. .
JOURNAL OF NANOMATERIALS, 2014, 2014
[3]   Synthesis of CuO nanostructures from Cu-based metal organic framework (MOE-199) for application as anode for Li-ion batteries [J].
Banerjee, Abhik ;
Singh, Upendra ;
Aravindan, Vanchiappan ;
Srinivasan, Madhavi ;
Ogale, Satishchandra .
NANO ENERGY, 2013, 2 (06) :1158-1163
[4]   Encapsulation of CuO nanoparticles inside the channels of the multi-walled carbon nanotubes functionalized with thermal stress [J].
Boran, Filiz .
DIAMOND AND RELATED MATERIALS, 2021, 114
[5]   Improvement of capacitance activity for Cu-doped Ni-based metal-organic frameworks by adding potassium hexacyanoferrate into KOH electrolyte [J].
Chen, Xiaoye ;
Wu, Xuemin ;
Guo, Hongxu ;
Fu, Wei .
APPLIED ORGANOMETALLIC CHEMISTRY, 2019, 33 (11)
[6]   Electrochemical supercapacitor studies of nanostructured α-MnO2 synthesized by microemulsion method and the effect of annealing [J].
Devaraj, S. ;
Munichandraiah, N. .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2007, 154 (02) :A80-A88
[7]   Fabrication and supercapacitive properties of a thick electrode of carbon nanotube-RuO2 core-shell hybrid material with a high RuO2 loading [J].
Fang, Hai-Tao ;
Liu, Min ;
Wang, Da-Wei ;
Ren, Xiao-Hui ;
Sun, Xue .
NANO ENERGY, 2013, 2 (06) :1232-1241
[8]   AgxMn8O16 Cathode Enables High-Performance Aqueous Li-Ion Hybrid Supercapacitors [J].
Hao, Chongyang ;
Chen, Lina ;
Zhang, Yamin ;
Zheng, Xiaowen ;
Li, Shanshan ;
Min, Guanghui ;
Ci, Lijie .
ENERGY & FUELS, 2021, 35 (18) :15101-15107
[9]   Polymer-wrapped reduced graphene oxide/nickel cobalt ferrite nanocomposites as tertiary hybrid supercapacitors: insights from experiment and simulation [J].
Hareesh, K. ;
Rondiya, Sachin R. ;
Dzade, Nelson Y. ;
Dhole, S. D. ;
Williams, Jim ;
Sergey, Samarin .
JOURNAL OF SCIENCE-ADVANCED MATERIALS AND DEVICES, 2021, 6 (02) :291-301
[10]   Temperature-Dependent supercapacitive behaviour of Cobalt oxide (Co3O4) nanospheres under electrolytes with different pH [J].
Jennifer, P. Joselene Suzan ;
Muthupandi, S. ;
Ruban, M. Joe Raja ;
Johxy, C. ;
Madhavan, J. ;
Prathap, S. ;
Raj, Victor Antony M. .
INORGANIC CHEMISTRY COMMUNICATIONS, 2022, 144