A novel class of new organic NLO hexamine: m-cresol material

被引:0
作者
Vijayalakshmi, S. [1 ]
Kalyanaraman, S. [1 ]
机构
[1] Sri Paramakalyani Coll, Post Grad & Res Dept Phys, Alwarkurichi, India
来源
OPTOELECTRONICS AND ADVANCED MATERIALS-RAPID COMMUNICATIONS | 2013年 / 7卷 / 7-8期
关键词
Organic material; Charge transfer (CT); Second harmonic generation (SHG); 2ND-HARMONIC GENERATION; HYDROGEN-BONDS; CRYSTALS; GROWTH; CHROMOPHORES;
D O I
暂无
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The new organic NLO material of hexamine: m - cresol material (1:2) has been synthesized by slow - evaporation technique. The good crystalline nature of the material is identified through Powder XRD analysis. FT - IR tool is used to confirm the formation of O - H - N hydrogen bonding and non proton transfer of the material. The charge transfer (CT) through hydrogen bonding is also established. The possible vibration modes are predicted through factor group analysis theoretically. The charge transfer interaction is confirmed by UV-Vis analysis in addition to the bathochromic shift behavior. That the candidate has greater second harmonic generation (SHG) efficiency than the KDP is identified through Powder Kurtz - Perry technique.
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页码:545 / 548
页数:4
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