Palladium(II), copper(II), iron(III), and vanadium(V) complexes with heteropolyanion PW9O349-:: 31P, 183W, 51V NMR and IR spectroscopy studies

被引：7

作者：

Detusheva, LG ^{[1
]}

Kuznetsova, LI ^{[1
]}

Fedotov, MA ^{[1
]}

Likholobov, VA ^{[1
]}

Dovlitova, LS ^{[1
]}

Vlasov, AA ^{[1
]}

Malakhov, VV ^{[1
]}

机构：

[1] Russian Acad Sci, Boreskov Inst Catalysis, Siberian Div, Novosibirsk 630090, Russia

来源：

RUSSIAN JOURNAL OF COORDINATION CHEMISTRY | 2001年 / 27卷 / 12期

关键词：

D O I：

10.1023/A:1013056927629

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The formation of Pd(II)-containing and mixed Pd(II),Cu(II), Pd(II),Fe(III), and Pd(II),V(V) complexes with heteropolyanion PW9O349- was studied using P-31, W-183, V-51 NMR, visible UV and IR spectroscopy, and the differentiating dissolution methods. In an aqueous solution and at optimal pH (3.7), the monometallic complexes [Pd-3(PW9O34)(2)](12-) and [Pd-3(PW9O34)(2)PdnOxHy](q-) (n(av) = 3), the bimetallic complexes [Pd2Cu(PW9O34)(2)](12-), [Pd2Fe(PW9O34)(2)](11-), and [PdFe2(PW9O34)(2)](10-), and a mixture of the [Pd-3(PW9O34)(2)PdnOxHy](q-) (n(av) = 10) + [(VO)(3)(PW9O34)(2)](9-) complexes are formed. The title complexes were isolated from solution as Cs+ solid salts belonging to the same [M-3(PW9O34)(2)] structural type.

引用

页码：838 / 845

页数：8

共 9 条

[1] Palladium(II), Copper(II), Iron(III), and Vanadium(V) Complexes with Heteropolyanion PW9O9–34: 31P, 183W, 51V NMR and IR Spectroscopy Studies
L. G. Detusheva
L. I. Kuznetsova
M. A. Fedotov
V. A. Likholobov
L. S. Dovlitova
A. A. Vlasov
V. V. Malakhov
Russian Journal of Coordination Chemistry, 2001, 27 : 838 - 845
[2] SYNTHESIS　AND　183W，51V　NMR　CHARACTERIZATION　OF　a－［GaW9V8O（40）］（5－）　HETEROPOLYANION
Xiao Peng ZHAN and Jing Fu LIU(Department of Chemistry Northeast Normal University
Chinese Chemical Letters, 1994, (07) : 603 - 604
[3] Bimetallic palladium(II) and iron(III), titanium(IV), vanadium(V), cobalt(II), and copper(II) complexes with the [As2W19O67(H2O)]14− heteropolyanion
L. G. Detusheva
L. I. Kuznetsova
N. I. Kuznetsova
L. S. Dovlitova
A. A. Vlasov
V. A. Likholobov
Russian Journal of Inorganic Chemistry, 2008, 53
[4] Bimetallic palladium(II) and iron(III), titanium(IV), vanadium(V), cobalt(II), and copper(II) complexes with the [As2W19O67(H2O)]14- heteropolyanion
Detusheva, L. G.
Kuznetsova, L. I.
Kuznetsova, N. I.
Dovlitova, L. S.
Vlasov, A. A.
Likholobov, V. A.
RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2008, 53 (05) : 690 - 695
[5] IRON(III) COMPLEXES WITH PW11O39(7-) HETEROPOLYANION IN AQUEOUS-SOLUTIONS BY SPECTROSCOPIC P-31, O-17, W-183 NMR, IR AND OPTICAL SPECTROSCOPY DATA
FEDOTOV, MA
DETUSHEVA, LG
KUZNETSOVA, LI
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ZHURNAL NEORGANICHESKOI KHIMII, 1993, 38 (03): : 515 - 525
[6] Synthesis and 183W and 51V NMR characterization of α- and β-K6H[GeW9V3O4O40]•xH2O and ESR spectra of mixed-valence vanadium polyanions
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So, HS
SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY, 1998, 28 (06): : 863 - 871
[7] Lanthanide complexes of the α-1 isomer of the [P2W17O61]10- heteropolytungstate:: Preparation, stoichiometry, and structural characterization by 183W and 31P NMR spectroscopy and europium(III) luminescence spectroscopy
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INORGANIC CHEMISTRY, 1999, 38 (06) : 1042 - 1053
[8] Dawson type heteropolyanions.: 3.: Syntheses and 31p, 51V, and 183W NMR structural investigation of octadeca(molybdo-tungsto-vanado)diphosphates related to the [H2P2W12O48]12- anion
Contant, R
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INORGANIC CHEMISTRY, 2004, 43 (12) : 3597 - 3604
[9] TRISUBSTITUTED HETEROPOLYTUNGSTATES AS SOLUBLE METAL-OXIDE ANALOGS .3. SYNTHESIS, CHARACTERIZATION, P-31, SI-29, V-51, AND 1-D AND 2-D W-183 NMR, DEPROTONATION, AND H+ MOBILITY STUDIES OF ORGANIC-SOLVENT SOLUBLE FORMS OF HXSIW9V3O40X-7 AND HXP2W15V3O62X-9
FINKE, RG
RAPKO, B
SAXTON, RJ
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