Studies on the intermolecular interactions in the binary mixtures of nitrobenzene with 2-methoxyethanol, 2-ethoxyethanol, 2-propoxyethanol and 2-butoxyethanol at T=298.15 K

被引：18

作者：

Kinart, Cezary M. ^{[1
]}

Cwiklinska, Aneta ^{[1
]}

Kinart, Zdzislaw ^{[1
]}

Bald, Adam ^{[1
]}

Kinart, Wojciech J. ^{[2
]}

机构：

[1] Univ Lodz, Dept Phys Chem Solut, PL-90236 Lodz, Poland

[2] Univ Lodz, Dept Organ Chem, PL-91403 Lodz, Poland

来源：

PHYSICS AND CHEMISTRY OF LIQUIDS | 2012年 / 50卷 / 05期

关键词：

nitrobenzene; 2-methoxyethanol; 2-ethoxyethanol; 2-propxyethanol; 2-butoxyethanol; density; viscosity; speed of sound; intermolecular interactions; EXCESS MOLAR VOLUMES; ISENTROPIC COMPRESSIBILITIES; DIFFERENT TEMPERATURES; N-ALKOXYETHANOLS; REFRACTIVE-INDEX; PHYSICOCHEMICAL PROPERTIES; THERMODYNAMIC PROPERTIES; RELATIVE PERMITTIVITIES; VISCOSITY DEVIATIONS; ORGANIC-SOLVENTS;

D O I：

10.1080/00319104.2012.712971

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Densities, viscosities and speeds of sound, at T = 298.15 K, in the binary mixtures of nitrobenzene with 2-methoxyethanol, 2-ethoxyethanol, 2-propoxyethanol and 2-butoxyethanol have been measured as a function of composition. From the experimental data excess molar volumes V E, excess energies of activation for viscous flow (G*(E)), excess isentropic compressibility (kappa(E)(S)) and the deviations in the viscosity (Delta ln eta) from a mole fraction average have been calculated. The viscosity data were correlated with equations of Hind et al., Grunberg and Nissan, Frenkel, and McAllister. The results are discussed in terms of intermolecular interactions and structure of studied binary mixtures.

引用

页码：679 / 696

页数：18

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