A porous Mn(v) coordination framework with PtS topology: assessment of the influence of a terminal nitride on CO2 sorption

被引:11
作者
Murphy, Michael J. [1 ]
D'Alessandro, Deanna M. [1 ]
Kepert, Cameron J. [1 ]
机构
[1] Univ Sydney, Sch Chem, Sydney, NSW 2006, Australia
基金
澳大利亚研究理事会;
关键词
METAL-ORGANIC FRAMEWORKS; CARBON-DIOXIDE CAPTURE; PRUSSIAN BLUE ANALOGS; SITU INFRARED TECHNIQUES; METHANOL CHEMISORPTION; HYDROGEN STORAGE; OXIDE CATALYSTS; ACTIVE-SITES; QUANTIFICATION; ADSORPTION;
D O I
10.1039/c3dt51721g
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
A new coordination framework material, [Zn{MnN(CN)(4)(H2O)}]center dot 2H(2)O center dot MeOH, has been characterised crystallographically and the effect of a terminal nitride on the N-2, H-2 and CO2 sorption capacities of the material assessed through porosimetery measurements and DRIFTS.
引用
收藏
页码:13308 / 13310
页数:3
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