Synthesis, crystal structure and magnetic property of copper(II) complex with 4′-cyanobenzyl-1-imidazol

被引：2
|
作者：
Sun, WY [1 ]
Fei, BL
Zhang, YA
Ye, T
Yu, KB
机构：
[1] Nanjing Univ, State Key Lab Coordinat Chem, Inst Coordinat Chem, Nanjing 210093, Peoples R China
[2] Chinese Acad Sci, Chengdu Branch, Anal Ctr, Chengdu 610041, Peoples R China
来源：
JOURNAL OF COORDINATION CHEMISTRY | 2002年 / 55卷 / 06期
基金：
中国国家自然科学基金;
关键词：
copper(II) complex; 4 '-cyanobenzyl-1-imidazol; crystal structure; magnetic property;
D O I：
10.1080/00958970290027543a
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A neutral mononuclear complex [Cu(cbIM)(4)(NO3)(2)] (cbIm=4'-cyanobenzyl-1-imidazol) was synthesized and characterized by x-ray crystallography. It crystallizes in the triclinic space group P-1 with a=8.249(2), b=8.735(2), c=16.597(2) Angstrom, alpha=81.980(10), beta=88.540(10), gamma=63.570(10)degrees and Z=2. The final refinement of the structure leads to R and Rw of 0.0394 and 0.0991, respectively. The crystal structure of the complex indicates a distorted octahedral environment around the Cu(II) atom, coordinated by four imidazole N atoms of four cbIm and two O atoms of two nitrates. Magnetic measurements show that the complex exhibits Curie behavior.
引用
收藏
页码：675 / 680
页数：6
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