Chiral separations in food analysis

被引:62
作者
Rocco, Anna [1 ]
Aturki, Zeineb [1 ]
Fanali, Salvatore [1 ]
机构
[1] Italian Natl Council Research, Inst Chem Methodol, I-00015 Rome, Italy
关键词
Adulteration; Amino acid; Beverage analysis; Chiral; Electromigration; Enantiomer; Food analysis; High-performance liquid chromatography; Nano-liquid chromatography; Polyphenol; PERFORMANCE LIQUID-CHROMATOGRAPHY; TANDEM MASS-SPECTROMETRY; AMINO-ACID ENANTIOMERS; LIGAND-EXCHANGE CE; DRY WHITE WINES; GAS-CHROMATOGRAPHY; ENANTIOSELECTIVE DETERMINATION; CAPILLARY-ELECTROPHORESIS; ELECTROMIGRATION METHODS; VOLATILE COMPOSITION;
D O I
10.1016/j.trac.2013.05.022
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
Analysis and determination of enantiomers is attractive in food chemistry, as, for example, the presence of D-amino acids can indicate adulteration, as only the natural (L)-isomer should be present in fruit juices. We highlight the importance of analyzing enantiomers in food, describe the general principle of enantiomer resolution and review the main applications in the past five years in food and beverage analysis. We consider high-performance separation methods (gas and liquid chromatography) and recently developed miniaturized tools (capillary electromigration and nano liquid chromatography). (C) 2013 Elsevier Ltd. All rights reserved.
引用
收藏
页码:206 / 225
页数:20
相关论文
共 77 条
[21]   Enantioselective Analysis of Triazole Fungicide Myclobutanil in Cucumber and Soil under Different Application Modes by Chiral Liquid Chromatography/Tandem Mass Spectrometry [J].
Dong, Fengshou ;
Cheng, Li ;
Liu, Xingang ;
Xu, Jun ;
Li, Jing ;
Li, Yuanbo ;
Kong, Zhiqiang ;
Jian, Qiu ;
Zheng, Yongquan .
JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY, 2012, 60 (08) :1929-1936
[22]   Selective determination of catechin, epicatechin and ascorbic acid in human urine using chiral capillary electrophoresis [J].
Ei-Hady, Deia Abd ;
Gotti, Roberto ;
Ei-Maali, Nagwa Abo .
JOURNAL OF SEPARATION SCIENCE, 2008, 31 (12) :2252-2259
[23]   High-throughput comprehensive analysis of D- and L-amino acids using ultra-high performance liquid chromatography with a circular dichroism (CD) detector and its application to food samples [J].
Eto, Sachise ;
Yamaguchi, Mai ;
Bounoshita, Masao ;
Mizukoshi, Toshimi ;
Miyano, Hiroshi .
JOURNAL OF CHROMATOGRAPHY B-ANALYTICAL TECHNOLOGIES IN THE BIOMEDICAL AND LIFE SCIENCES, 2011, 879 (29) :3317-3325
[24]   Comparative performance of capillary columns made with totally porous and core-shell particles coated with a polysaccharide-based chiral selector in nano-liquid chromatography and capillary electrochromatography [J].
Fanali, Salvatore ;
D'Orazio, Giovanni ;
Farkas, Tivadar ;
Chankvetadze, Bezhan .
JOURNAL OF CHROMATOGRAPHY A, 2012, 1269 :136-142
[25]   Enantiomeric and non-enantiomeric monoterpenes of Juniperus communis L. and Juniperus oxycedrus needles and berries determined by HS-SPME and enantioselective GC/MS [J].
Foudil-Cherif, Yazid ;
Yassaa, Noureddine .
FOOD CHEMISTRY, 2012, 135 (03) :1796-1800
[26]   Chiral analysis of amino acids from conventional and transgenic yeasts [J].
Giuffrida, Alessandro ;
Tabera, Laura ;
Gonzalez, Ramon ;
Cucinotta, Vincenzo ;
Cifuentes, Alejandro .
JOURNAL OF CHROMATOGRAPHY B-ANALYTICAL TECHNOLOGIES IN THE BIOMEDICAL AND LIFE SCIENCES, 2008, 875 (01) :243-247
[27]   Modified cyclodextrins for fast and sensitive chiral-capillary electrophoresis-mass spectrometry [J].
Giuffrida, Alessandro ;
Leon, Carlos ;
Garcia-Canas, Virginia ;
Cucinotta, Vincenzo ;
Cifuentes, Alejandro .
ELECTROPHORESIS, 2009, 30 (10) :1734-1742
[28]   High-performance liquid chromatography analysis of naturally occurring D-amino acids in sake [J].
Gogami, Yoshitaka ;
Okada, Kaori ;
Oikawa, Tadao .
JOURNAL OF CHROMATOGRAPHY B-ANALYTICAL TECHNOLOGIES IN THE BIOMEDICAL AND LIFE SCIENCES, 2011, 879 (29) :3259-3267
[29]   Differentiation of green tea samples by chiral CD-MEKC analysis of catechins content [J].
Gotti, Roberto ;
Furlanetto, Sandra ;
Lanteri, Silvia ;
Olmo, Stefano ;
Ragaini, Alessandro ;
Cavrini, Vanni .
ELECTROPHORESIS, 2009, 30 (16) :2922-2930
[30]   Stereoselective degradation of benalaxyl in tomato, tobacco, sugar beet, capsicum, and soil [J].
Gu, Xu ;
Wang, Peng ;
Liu, Donghui ;
Lv, Chunguang ;
Lu, Yuele ;
Zhou, Zhiqiang .
CHIRALITY, 2008, 20 (02) :125-129