Chiral separations in food analysis

被引：62

作者：

Rocco, Anna ^{[1
]}

Aturki, Zeineb ^{[1
]}

Fanali, Salvatore ^{[1
]}

机构：

[1] Italian Natl Council Research, Inst Chem Methodol, I-00015 Rome, Italy

来源：

TRAC-TRENDS IN ANALYTICAL CHEMISTRY | 2013年 / 52卷

关键词：

Adulteration; Amino acid; Beverage analysis; Chiral; Electromigration; Enantiomer; Food analysis; High-performance liquid chromatography; Nano-liquid chromatography; Polyphenol; PERFORMANCE LIQUID-CHROMATOGRAPHY; TANDEM MASS-SPECTROMETRY; AMINO-ACID ENANTIOMERS; LIGAND-EXCHANGE CE; DRY WHITE WINES; GAS-CHROMATOGRAPHY; ENANTIOSELECTIVE DETERMINATION; CAPILLARY-ELECTROPHORESIS; ELECTROMIGRATION METHODS; VOLATILE COMPOSITION;

D O I：

10.1016/j.trac.2013.05.022

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

Analysis and determination of enantiomers is attractive in food chemistry, as, for example, the presence of D-amino acids can indicate adulteration, as only the natural (L)-isomer should be present in fruit juices. We highlight the importance of analyzing enantiomers in food, describe the general principle of enantiomer resolution and review the main applications in the past five years in food and beverage analysis. We consider high-performance separation methods (gas and liquid chromatography) and recently developed miniaturized tools (capillary electromigration and nano liquid chromatography). (C) 2013 Elsevier Ltd. All rights reserved.

引用

页码：206 / 225

页数：20

共 77 条

[1] Gas chromatographic determination of amino acid enantiomers in bottled and aged wines [J].

Ali, Hatem Salama Mohammed ;

Paetzold, Ralf ;

Brueckner, Hans .

AMINO ACIDS, 2010, 38 (03) :951-958

[2] RELEVANCE OF ENANTIOMERIC SEPARATIONS IN FOOD AND BEVERAGE ANALYSES [J].

ARMSTRONG, DW ;

CHANG, CD ;

LI, WY .

JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY, 1990, 38 (08) :1674-1677

[3] Food analysis: A continuous challenge for miniaturized separation techniques [J].

Asensio-Ramos, Maria ;

Hernandez-Borges, Javier ;

Rocco, Anna ;

Fanali, Salvatore .

JOURNAL OF SEPARATION SCIENCE, 2009, 32 (21) :3764-3800

[4] Development of an in-capillary derivatization method by CE for the determination of chiral amino acids in dietary supplements and wines [J].

Belen Martinez-Giron, Ana ;

Garcia-Ruiz, Carmen ;

Crego, Antonio L. ;

Luisa Marina, Maria .

ELECTROPHORESIS, 2009, 30 (04) :696-704

[5] Conventional and narrow bore short capillary columns with cyclodextrin derivatives as chiral selectors to speed-up enantioselective gas chromatography and enantioselective gas chromatography-mass spectrometry analyses [J].

Bicchi, Carlo ;

Liberto, Erica ;

Cagliero, Cecilia ;

Cordero, Chiara ;

Sgorbini, Barbara ;

Rubiolo, Patrizia .

JOURNAL OF CHROMATOGRAPHY A, 2008, 1212 (1-2) :114-123

[6] New asymmetrical per-substituted cyclodextrins (2-O-methyl-3-O-ethyl- and 2-O-ethyl-3-O-methyl-6-O-t-butyldimethylsilyl-β-derivatives) as chiral selectors for enantioselective gas chromatography in the flavour and fragrance field [J].

Bicchi, Carlo ;

Cagliero, Cecilia ;

Liberto, Erica ;

Sgorbini, Barbara ;

Martina, Katia ;

Cravotto, Giancarlo ;

Rubiolo, Patrizia .

JOURNAL OF CHROMATOGRAPHY A, 2010, 1217 (07) :1106-1113

[7] Racemization at C-2 of naringin in pummelo (Citrus grandis) with increasing maturity determined by chiral high-performance liquid chromatography [J].

Caccamese, Salvatore ;

Chillemi, Rosa .

JOURNAL OF CHROMATOGRAPHY A, 2010, 1217 (07) :1089-1093

[8] Fast headspace-enantioselective GC-mass spectrometric-multivariate statistical method for routine authentication of flavoured fruit foods [J].

Cagliero, Cecilia ;

Bicchi, Carlo ;

Cordero, Chiara ;

Rubiolo, Patrizia ;

Sgorbini, Barbara ;

Liberto, Erica .

FOOD CHEMISTRY, 2012, 132 (02) :1071-1079

[9] Quantification of salsolinol enantiomers by stable isotope dilution liquid chromatography with tandem mass spectrometric detection [J].

Cai, Min ;

Liu, Yi-Ming .

RAPID COMMUNICATIONS IN MASS SPECTROMETRY, 2008, 22 (24) :4171-4177

[10] Chiral MEKC-LIF of amino acids in foods: Analysis of vinegars [J].

Carlavilla, Davinia ;

Moreno-Arribas, M. Victoria ;

Fanali, Salvatore ;

Cifuentes, Alejandro .

ELECTROPHORESIS, 2006, 27 (13) :2551-2557

← 1 2 3 4 5 6 7 8 →