Synthesis and crystal structure of the bismuth complex [bi(S2CNC5H10)2(NO3)] • [1,10-phen] • 0.5H2O

被引：0

作者：

Yin, HD ^{[1
]}

Wang, CH ^{[1
]}

Xu, FQ ^{[1
]}

机构：

[1] Liaocheng Univ, Dept Chem, Liacheng 252059, Peoples R China

来源：

CHINESE JOURNAL OF INORGANIC CHEMISTRY | 2004年 / 20卷 / 03期

关键词：

bismuth complex; dithiopiperdylcarbamate; synthesis; crystal structure;

D O I：

暂无

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The bismuth complex with dithiopiperdylcarbamate [Bi(S2CNC5H10)(2)(NO3)].[1,10-Phen].0.5H(2)O was synthesized. The crystal and molecular structure were determined by X-ray single crystal diffraction. The crystal belongs to monoiclinic with space group C2/c, a=3.140(2) nm, b=1.176 4(9) nm, c=2.021 6(15) nm, beta=103.081(12)degrees, V= 5.713(7) nm(3), Z=8, F(000)=3 064, D-c=1.815 g(.)cm(-3), mu=6.502mm(-1). The final R-1=0.033 2, wR(2)=0.040 3. In the complex, the bismuth atom is eight-coordinated in a capped distorted pentagonal bipyramidal geometry.

引用

页码：345 / 348

页数：4

共 17 条

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