CuO Nanorods-Decorated Reduced Graphene Oxide Nanocatalysts for Catalytic Oxidation of CO

被引:34
作者
Wang, Yan [1 ]
Wen, Zhihui [1 ]
Zhang, Huoli [2 ]
Cao, Guohua [2 ]
Sun, Qi [2 ]
Cao, Jianliang [2 ]
机构
[1] Henan Polytech Univ, State Key Lab Cultivat Base Gas Geol & Gas Contro, Sch Safety Sci & Engn, Jiaozuo 454000, Peoples R China
[2] Henan Polytech Univ, Sch Chem & Chem Engn, Jiaozuo 454000, Peoples R China
基金
中国国家自然科学基金; 中国博士后科学基金;
关键词
CuO nanorods; reduced graphene oxide; heterogeneous catalysis; CO; catalytic oxidation; LOW-TEMPERATURE; CARBON-MONOXIDE; PERFORMANCE; TIO2;
D O I
10.3390/catal6120214
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Developing an efficient non-noble catalyst for CO oxidation with high catalytic activity remains a challenge for practical applications. In this work, CuO nanorods decorated reduced graphene oxide (RGO) nanocatalysts were prepared via a facile one-step hydrothermal method. The structure and morphology of the as-prepared samples were characterized by XRD, Raman spectroscopy, SEM, TEM, and X-ray photoelectron spectroscopy (XPS). The analysis results show that CuO nanorods were successfully deposited on the surface of RGO sheets with the length of 250-500 nm. The catalytic properties of the as-prepared catalysts for CO oxidation were evaluated by using a microreactor-gas chromatograph (GC) system. The as-prepared RGO-CuO nanocatalysts exhibited high activity for CO oxidation, and the 10 wt % reduced graphene oxide content catalyst can achieve CO total oxidation at 165 degrees C.
引用
收藏
页数:8
相关论文
共 34 条
[1]   Effect of the preparation method and calcination temperature on the oxidation activity of CO at low temperature on CuO-CeO2/SiO2 catalysts [J].
Aguila, Gonzalo ;
Guerrero, Sichem ;
Araya, Paulo .
APPLIED CATALYSIS A-GENERAL, 2013, 462 :56-63
[2]   Catalytic performance and characterization of Au/doped-ceria catalysts for the preferential CO oxidation reaction [J].
Avgouropoulos, G. ;
Manzoli, M. ;
Boccuzzi, F. ;
Tabakova, T. ;
Papavasiliou, J. ;
Ioannides, T. ;
Idakiev, V. .
JOURNAL OF CATALYSIS, 2008, 256 (02) :237-247
[3]   Mesoporous CuO-Fe2O3 composite catalysts for low-temperature carbon monoxide oxidation [J].
Cao, Jian-Liang ;
Wang, Yan ;
Yu, Xiu-Ling ;
Wang, Shu-Rong ;
Wu, Shi-Hua ;
Yuan, Zhong-Yong .
APPLIED CATALYSIS B-ENVIRONMENTAL, 2008, 79 (1-2) :26-34
[4]   Preparation, characterization and catalytic behavior of nanostructured mesoporous CuO/Ce0.8Zr0.2O2 catalysts for low-temperature CO oxidation [J].
Cao, Jian-Liang ;
Wang, Yan ;
Zhang, Tong-Ying ;
Wu, Shi-Hua ;
Yuan, Zhong-Yong .
APPLIED CATALYSIS B-ENVIRONMENTAL, 2008, 78 (1-2) :120-128
[6]   Synthesis of Pd/Fe3O4 Hybrid Nanocatalysts with Controllable Interface and Enhanced Catalytic Activities for CO Oxidation [J].
Chen, Shutang ;
Si, Rui ;
Taylor, Eric ;
Janzen, Jonathan ;
Chen, Jingyi .
JOURNAL OF PHYSICAL CHEMISTRY C, 2012, 116 (23) :12969-12976
[7]   Controlling the CO oxidation rate over Pt/TiO2 catalysts by defect engineering of the TiO2 support [J].
Chua, Y. P. Gavin ;
Gunasooriya, G. T. Kasun Kalhara ;
Saeys, Mark ;
Seebauer, Edmund G. .
JOURNAL OF CATALYSIS, 2014, 311 :306-313
[8]  
Engel T., 1979, ADV CATALYSIS VOLUME, V28, P1, DOI DOI 10.1016/S0360-0564(08)60133-9
[9]   Novel Strategy for Preparation of Graphene-Pd, Pt Composite, and Its Enhanced Electrocatalytic Activity for Alcohol Oxidation [J].
Gao, Lina ;
Yue, Wenbo ;
Tao, Shanshan ;
Fan, Louzhen .
LANGMUIR, 2013, 29 (03) :957-964
[10]   Cyclodextrin Functionalized Graphene Nanosheets with High Supramolecular Recognition Capability: Synthesis and Host-Guest Inclusion for Enhanced Electrochemical Performance [J].
Guo, Yujing ;
Guo, Shaojun ;
Ren, Jiangtao ;
Zhai, Yueming ;
Dong, Shaojun ;
Wang, Erkang .
ACS NANO, 2010, 4 (07) :4001-4010