Lanthanide-Based Coordination Polymers with a 4,5-Dichlorophthalate Ligand Exhibiting Highly Tunable Luminescence: Toward Luminescent Bar Codes

被引：70

作者：

Badiane, Albert-Manga ^{[1
]}

Freslon, Stephane ^{[2
]}

Daiguebonne, Carole ^{[2
]}

Suffren, Yan ^{[2
]}

Bernot, Kevin ^{[2
]}

Calvez, Guillaume ^{[2
]}

Costuas, Karine ^{[2
]}

Camara, Magatte ^{[1
]}

Guillou, Olivier ^{[2
]}

机构：

[1] Chim Douce & Cristallog Univ Assane Seck Ziguinch, LCPM Grp Mat Inorgan, BP 523, Ziguinchor, Senegal

[2] Univ Rennes, INSA Rennes, CNRS, ISCR, F-35708 Rennes, France

来源：

INORGANIC CHEMISTRY | 2018年 / 57卷 / 06期

关键词：

METAL-ORGANIC FRAMEWORKS; CRYSTAL-STRUCTURES; COLOR TUNABILITY; ENERGY-TRANSFER; COMPLEXES; BRIGHTNESS; PROGRAM; FAMILY; IMAGES; LEVEL;

D O I：

10.1021/acs.inorgchem.8b00169

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reactions in water of 4,5-dichlorophthalate (dcpa(2-)) with the heaviest lanthanide ions lead to a family of compounds with the general chemical formula [Ln(2)(dcpa)(3)(H2O)(5)center dot 3H(2)O](infinity), where Ln = Tb-Lu, Y. The synthesis, crystal structure, thermal behavior, and luminescent properties of this series of homonuclear compounds are described. Additionally, this family can be extended to isostructural heteronuclear compounds that can contain some light lanthanide ions and therefore present some original photophysical properties. These compounds show potential interest as multiemissive materials (visible and infrared light between 450 and 1600 nm) and could find application as luminescent bar codes.

引用

页码：3399 / 3410

页数：12

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