Adsorption and photocatalytic degradation of 2,4-dichlorophenol in TiO2 suspensions. Effect of hydrogen peroxide, sodium peroxodisulphate and ozone

被引：43

作者：

Pulido Melian, E. ^{[1
]}

Gonzalez Diaz, O. ^{[1
]}

Dona Rodriguez, J. M. ^{[1
]}

Arana, J. ^{[1
]}

Perez Pena, J. ^{[1
]}

机构：

[1] Univ Las Palmas Gran Canaria, Ctr Instrumental Quim Fis Desarrollo Invest Aplic, Las Palmas Gran Canaria, Spain

来源：

APPLIED CATALYSIS A-GENERAL | 2013年 / 455卷

关键词：

Photocatalysis; TiO2, 2,4-dichlorophenol; Hydrogen peroxide; Ozone; Peroxodisulphate; ORGANIC CONTAMINANTS; PHOTODEGRADATION; HERBICIDES; OZONATION; OXIDATION; KINETICS; WATER; MINERALIZATION; TRANSFORMATION; DECOMPOSITION;

D O I：

10.1016/j.apcata.2013.02.007

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

2,4-dichlorophenol (DCP) was decomposed in the presence of TiO2 suspensions by illumination. The operating variables that were studied included initial DCP concentration, photocatalyst doses and initial pH. Mineralisation was slow at the optimum pH (12) for DCP degradation, with the optimum pH for both degradation and mineralisation being pH(o) 5. The kinetic patterns were fitted to a first order kinetic. Adsorption and rate constants were obtained by using the Langmuir-Hinshelwood model. The adsorption isotherm was fitted to the Freundlich model and the Langmuir model with high coefficients of correlation. The adsorption constant in darkness was lower than that obtained with the kinetic model.According to the FTIR results, DCP-TiO2 interaction occurs as a result of the formation of a phenolate. Of the three oxidants tested - hydrogen peroxide, ozone and sodium peroxodisulphate - only H2O2 resulted in enhancement of the photocatalytic process. (c) 2013 Elsevier B.V. All rights reserved.

引用

页码：227 / 233

页数：7

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