Synthesis and characterization of rare earth complexes with a bis-Schiff base from salicylaldehyde and 1,6-hexanediamine

被引：0

作者：

Yu, Yuye ^{[1
]}

Zhao, Guoliang ^{[1
]}

机构：

[1] Jinhua Coll Profess & Technol, Normal Coll, Jinhua 321017, Peoples R China

来源：

ASIAN JOURNAL OF CHEMISTRY | 2008年 / 20卷 / 04期

关键词：

salicyladehyde; 1,6-hexanediamine; Schiff base; rare earth complexes;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A series of lanthanide(III) complexes of the type [LnL(2)Cl(2)]Cl, where Ln = La, Ce, Pr, Nd, Sm, Eu, Gd,Tb, Dy, Ho, Er, Tm, Yb, Lu, L = C20H24N2O2, a bis-Schiff base ligand derived from salicylaldehyde and 1,6-hexanediamine, have been synthesized and characterized by elemental analyses, molar electrical conductivities, infrared and electronic spectra, thermergravimetric analyses.-All the complexes were found to be 1: 1 electrolytes of the general empirical formula [LnL(2)Cl(2)]Cl. The Schiff base ligand behaves as tetradentate ligand having a N2O2 donor sets towards the metal cations. A probable coordination number ten has been assigned in these complexes.

引用

页码：2763 / 2768

页数：6

共 50 条

[31] Synthesis and Characterization of New Schiff Base and Polyoxa-azaCryptands and Their Rare Earth Cryptates with [1+1] Condensation and Reduction Methods
Zhen MA
Ru Dong YANG
Lan YAN(Department of Chemistry
Chinese Chemical Letters, 1999, (12) : 995 - 998
[32] Synthesis, Characterization and Activity of Rare Earth Complexes with Schiff Base From 2,6-Diformylpyridine N-Oxide and 4-Amino-antipyrine
于青
唐瑜
谭民裕
Journal of Rare Earths, 2002, (05) : 385 - 387
[33] Synthesis and characterization of managanese(II) complexes of Schiff base derived from pyrazinamide
Budhani, P
Iqbal, SA
ASIAN JOURNAL OF CHEMISTRY, 2005, 17 (04) : 2833 - 2835
[34] In vitro antimicrobial and antioxidant evaluation of rare earth metal Schiff base complexes derived from threonine
Logu, Lekha
Kamatchi, Kanmani Raja
Rajmohan, Hariharan
Manohar, Sathish
Gurusamy, Rajagopal
Deivanayagam, Easwaramoorthi
APPLIED ORGANOMETALLIC CHEMISTRY, 2015, 29 (02) : 90 - 95
[35] Synthesis, Crystal Structure, and Antimicrobial Activity of Manganese(III) and Iron(III) Complexes Derived from Similar bis-Schiff Bases
Pan, Zi-Hong
Zhao, Gan-Qing
Xue, Ling-Wei
Yang, Wei-Chun
SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY, 2016, 46 (12) : 1759 - 1764
[36] Synthesis, structural characterization, and properties of triorganotin complexes of Schiff base derived from 3-aminobenzoic acid and salicylaldehyde or 2,4-pentanedione
Chen, Lexing
Wang, Zhengwei
Qiu, Tongguang
Sun, Ruikun
Zhao, Zhiyuan
Tian, Laijin
Liu, Xicheng
APPLIED ORGANOMETALLIC CHEMISTRY, 2020, 34 (09)
[37] Synthesis, characterization, and antibacterial activity of two zinc(II) complexes with Schiff bases from halogenated salicylaldehyde and amantadine
Q. Yang
C. Xu
G. C. Han
X. C. Liu
X. D. Jin
B. X. Wang
D. L. Liu
H. H. Hu
Russian Journal of Coordination Chemistry, 2014, 40 : 634 - 642
[38] Synthesis and characterization of new Schiff base and polyoxa-aza cryptands and their rare earth cryptates with [1+1] condensation and reduction methods
Ma, Z
Yang, RD
Yan, L
CHINESE CHEMICAL LETTERS, 1999, 10 (12) : 995 - 998
[39] Synthesis and characterization of thorium(IV) and dioxouranium(VI) complexes of a Schiff base: Part 1
Khan, AR
Sharma, KP
Arora, K
ASIAN JOURNAL OF CHEMISTRY, 2004, 16 (01) : 349 - 352
[40] Green synthesis of a novel bis-Schiff base derived from 4-N, N-dimethylaminobenzaldehyde and hexamethylenediamine: DFT study
Rezvan, Vahideh Hadigheh
Afsaneh, Alireza
JOURNAL OF MOLECULAR STRUCTURE, 2024, 1313

← 1 2 3 4 5 →