Adsorption study of RDX and TNT explosives in soils by HPLC

被引：10
作者：
Falone, Sandra Zago
Vieira, Eny Maria
Onuska, Francis I.
机构：
[1] Univ Sao Paulo, Inst Chem, BR-13560970 Sao Carlos, SP, Brazil
[2] Environm Canada, Natl Water Res Inst, Aquat Ecosyst Protect Branch, Burlington, ON, Canada
来源：
JOURNAL OF LIQUID CHROMATOGRAPHY & RELATED TECHNOLOGIES | 2006年 / 29卷 / 11期
基金：
巴西圣保罗研究基金会;
关键词：
explosives; adsorption; desorption; Freundlich;
D O I：
10.1080/10826070600678373
中图分类号：
Q5 [生物化学];
学科分类号：
071010 ; 081704 ;
摘要：
The environmental contamination by explosives has concerned the scientific community, due to their toxicity, mainly in those areas where the explosives are manufactured, stored, or still demilitarized. This paper describes the RDX and TNT interaction in different matrices. The Freundlich isotherms were used for the data mathematical treatment. The results indicated that the largest adsorption and the smallest desorption of the RDX and TNT explosives occurred in the peat in natura, with adsorption coefficient (Kd) of 24.88 and Freundlich dessorption value 37.56 of RDX explosive, and adsorption coefficient (Kd) 78.11 and Freundlich desorption value 110,31 of TNT explosive.
引用
收藏
页码：1645 / 1662
页数：18
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