Liquid Coordination Complexes Formed by the Heterolytic Cleavage of Metal Halides

被引：110

作者：

Coleman, Fergal ^{[1
]}

Srinivasan, Geetha ^{[1
]}

Swadzba-Kwasny, Malgorzata ^{[1
]}

机构：

[1] Queens Univ Belfast, QUILL Res Ctr, Belfast BT9 5AG, Antrim, North Ireland

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2013年 / 52卷 / 48期

关键词：

aluminum; gallium; Group; 13; ionic liquids; liquid coordination complexes; IONIC LIQUIDS; AMBIENT-TEMPERATURES; MASS-SPECTROMETRY; ALUMINUM-CHLORIDE; RAMAN-SPECTRA; SPECIATION; ELECTRODEPOSITION; TETRAHYDROFURAN;

D O I：

10.1002/anie.201306267

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Confused complexes: Reaction of a range of donor molecules with AlCl 3 or GaCl3, gives mobile liquids with very high metal contents. They contain statistically distributed mixtures of anionic, cationic, and neutral complexes in equilibrium. These liquid coordination complexes (LCCs), have high conductivity, tunable Lewis acidity, and low vapor pressure. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：12582 / 12586

页数：5

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