One-Step Synthesis of Unsymmetrical Sulfides Bearing Hexafluorocumyl Moiety

被引：0

作者：

Zajac, Adrian ^{[1
]}

Drabowicz, Jozef ^{[1
,2
]}

机构：

[1] Polish Acad Sci, Ctr Mol & Macromol Studies, Dept Heteroorgan Chem, PL-90363 Lodz, Poland

[2] Jan Dlugosz Univ Czestochowa, Dept Chem, Czestochowa, Poland

来源：

SYNTHETIC COMMUNICATIONS | 2013年 / 43卷 / 24期

关键词：

Alkyl-aryl sulfides; diaryl sulfides; hexafluorocumylalcohol; ortholithiation; unsymmetrical sulfides; CONVENIENT SYNTHESIS; DIALKYL SULFIDES; ALKYL-HALIDES; ARYL SULFIDES; S-S; DISULFIDES; CLEAVAGE; DISELENIDES; COMPLEXES; CATALYST;

D O I：

10.1080/00397911.2013.774018

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A facile and convenient one-pot synthesis of novel unsymmetrical sulfides, 2-alkylthio- and 2-arylthio-1,1,1,3,3,3-hexafluoro-2-phenylpropan-2-oles 1a-k, is presented. Physicochemical characterization; IR infrared; H-1, C-13, and F-19 NMR; and mass spectral analyses of the obtained compounds are discussed as well. [Supplementary materials are available for this article. Go to the publisher's online edition of Synthetic Communications (R) for the following free supplemental resource(s): Full experimental and spectral details.]

引用

页码：3287 / 3293

页数：7

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