Arene-perfluoroarene interactions in crystal engineering.: Part 14.: 1:1 Complexes of octafluoronaphthalene with fluorene and 9,10-dihydrophenanthrene

被引:20
作者
Collings, JC [1 ]
Batsanov, AS [1 ]
Howard, JAK [1 ]
Marder, TB [1 ]
机构
[1] Univ Durham, Dept Chem, Durham DH1 3LE, England
关键词
single crystal; X-ray structure; pi stacking; fluoroarene;
D O I
10.1139/V06-007
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The 1:1 molecular complexes of octafluoronaphthalene (OFN) with fluorene (1) and with 9,10-dihydrophenanthrene (2) were prepared by cocrystallization of the components and characterized by single-crystal X-ray diffraction. The structure of 1 can be described as a mixed-stack or a laminar checkerboard motif of alternating OFN and fluorene molecules, whilst slanted mixed-stack, herringbone, and face-to-face heteromolecular dimer motifs can all be recognised in 2.
引用
收藏
页码:238 / 242
页数:5
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