Formation of [(L)Ni(μ2-S)x{Fe(CO)3}x] adducts (x=1 or 2):: analogues of the active site of [NiFe] hydrogenase

被引：28
|
作者：
Stenson, PA [1 ]
Marin-Becerra, A [1 ]
Wilson, C [1 ]
Blake, AJ [1 ]
McMaster, J [1 ]
Schröder, M [1 ]
机构：
[1] Univ Nottingham, Sch Chem, Nottingham NG7 2RD, England
来源：
CHEMICAL COMMUNICATIONS | 2006年 / 03期
关键词：
D O I：
10.1039/b509798c
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The binuclear [Ni(L)Fe(CO)(3)], 1, and trinuclear [Ni(L){Fe(CO)(3)}(2)], 2, complexes adopt unusual structural motifs whereby Fe(CO)(3) units bind to [Ni(L)] via mu(2)-S bridging modes, C=N imine pi-bonds and potential Ni-Fe bonding interactions.
引用
收藏
页码：317 / 319
页数：3
相关论文
共 50 条
  • [1] STRUCTURE OF FE(110) 2 X 2-S
    SHIH, HD
    JONA, F
    MARCUS, PM
    BULLETIN OF THE AMERICAN PHYSICAL SOCIETY, 1980, 25 (03): : 327 - 327
  • [2] Advances in the preparation of redox active NiFe complexes based on NiN2S2-Fe(NO)2 as synthetic analogues of [NiFe]-hydrogenase enzyme active site
    Ghosh, Pokhraj
    Chupik, Rachel
    Hsieh, Chung-Hung
    Bhuvanesh, Nattamai
    Darensbourg, Marcetta
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2016, 252
  • [3] Reactions of laser-ablated Fe, Co, and Ni with NO:: Infrared spectra and density functional calculations of MNO+ and M(NO)x (M = Fe, Co, x=1-3; M = Ni, x=1, 2), and M(NO)x- (M = Co, Ni; x=1, 2)
    Zhou, MF
    Andrews, L
    JOURNAL OF PHYSICAL CHEMISTRY A, 2000, 104 (17): : 3915 - 3925
  • [4] [(C6H4S2)Ni(μ-'S3')Fe(CO)(PMe3)2]:: A dinuclear [NiFe] complex modeling the [(RS)2Ni(μ-SR)2Fe(CO)(L)2] core of [NiFe] hydrogenase centers
    Sellmann, D
    Geipel, F
    Lauderbach, F
    Heinemann, FW
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2002, 41 (04) : 632 - +
  • [5] Fundamental properties of organometallic analogues of the 2Fe2S active site in Fe-only hydrogenase
    Darensbourg, MY
    Lyon, EJ
    Georgakaki, I
    JOURNAL OF INORGANIC BIOCHEMISTRY, 2001, 86 (01) : 38 - 38
  • [6] Synthetic and structural studies on [Fe2(SR)2(CN)x(CO)6-x]x- as active site models for Fe-only hydrogenases
    Gloaguen, F
    Lawrence, JD
    Schmidt, M
    Wilson, SR
    Rauchfuss, TB
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (50) : 12518 - 12527
  • [7] Mossbauer studies of Ti-x(Fe(2-2x)M(1+x))O-4 and Ge-x(Fe(2-2x)M(1+x))O-4 (M=Co and Ni)
    ElOcker, MM
    Mostafa, MA
    Aly, HMT
    Mohamed, RL
    Saadoun, AST
    PHYSICA STATUS SOLIDI A-APPLIED RESEARCH, 1996, 158 (01): : 205 - 215
  • [8] Synthesis, X-ray structure and electrochemical characterisation of a binuclear thiolate bridged Ni-Fe-nitrosyl complex, related to the active site of NiFe hydrogenase
    Osterloh, F
    Saak, W
    Haase, D
    Pohl, S
    CHEMICAL COMMUNICATIONS, 1997, (10) : 979 - 980
  • [9] Removal of the bridging ligand atom at the Ni-Fe active site of [NiFe] hydrogenase upon reduction with H2, as revealed by X-ray structure analysis at 1.4 Å resolution
    Higuchi, Y
    Ogata, H
    Miki, K
    Yasuoka, N
    Yagi, T
    STRUCTURE WITH FOLDING & DESIGN, 1999, 7 (05): : 549 - 556
  • [10] THE EVIDENCE OF CDX2+FE1-X3+[NI1-X2+FE1+X3+]O4 CATION DISTRIBUTION BASED ON X-RAY AND MOSSBAUER DATA
    WOLSKA, E
    RIEDEL, E
    WOLSKI, W
    PHYSICA STATUS SOLIDI A-APPLIED RESEARCH, 1992, 132 (01): : K51 - K56
12345