Mathematic modelling of the peculiarities of NO decomposition on Rh(111)

被引：26
|
作者：
Makeev, A
Slinko, MM
机构：
[1] RUSSIAN ACAD SCI,INST CHEM PHYS,MOSCOW 117334,RUSSIA
[2] MOSCOW MV LOMONOSOV STATE UNIV,DEPT COMP MATH & CYBERNET,MOSCOW 119899,RUSSIA
来源：
SURFACE SCIENCE | 1996年 / 359卷 / 1-3期
关键词：
computer simulations; low index single crystal surfaces; models of surface kinetics; nitrogen oxide; rhodium; thermal desorption;
D O I：
10.1016/0039-6028(96)00677-2
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The complicated reaction kinetics of NO desorption and decomposition were adequately simulated within the framework of a deterministic model considering interactions in the adsorbed layer. The repulsive interactions between N and NO adparticles together with the strong inhibition of NO dissociation by NO, N and O adsorbates were shown to be responsible for the peculiarities of N-2 and NO TPD spectra from the Rh(111) surface.
引用
收藏
页码：L467 / L472
页数：6
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