Silver solid amalgam electrodes as sensors for chemical carcinogens

被引:93
作者
Barek, J [1 ]
Fischer, J
Navratil, T
Peckova, K
Yosypchuk, B
机构
[1] Charles Univ, Dept Analyt Chem, UNESCO Lab Environm Electrochem, Prague 12843 2, Czech Republic
[2] Acad Sci Czech Republ, J Heyrovsky Inst Phys Chem, Prague 18223 8, Czech Republic
关键词
solid amalgam electrodes; voltammetry; carcinogens; 3-nitrofluoranthene; Ostazine Orange;
D O I
10.3390/s6040445
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
The applicability of differential pulse voltammetry (DPV) and adsorptive stripping voltammetry (AdSV) at a non-toxic meniscus-modified silver solid amalgam electrode (m-AgSAE) for the determination of trace amounts of genotoxic substances was demonstrated on the determination of micromolar and submicromolar concentrations of 3-nitrofluoranthene using methanol - 0.01 mol L-1 NaOH ( 9: 1) mixture as a base electrolyte and of Ostazine Orange using 0.01 mol L-1 NaOH as a base electrolyte.
引用
收藏
页码:445 / 452
页数:8
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