Kinetic characterization of spiropyrans in aqueous media

被引：94

作者：

Stafforst, Thorsten ^{[1
]}

Hilvert, Donald ^{[1
]}

机构：

[1] ETH, Organ Chem Lab, CH-8093 Zurich, Switzerland

来源：

CHEMICAL COMMUNICATIONS | 2009年 / 03期

关键词：

D O I：

10.1039/b818050d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Detailed kinetic investigations of the most common photo-switchable spiropyran, 6-nitro-BIPS, reveal that hydrolytic decomposition of its merocyanine isomer limits its utility in aqueous buffer; however, simple replacement of the 6-nitro substituent with an 8-carboxylate yields a BIPS photoswitch that is potentially better suited for biological applications.

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页码：287 / 288

页数：2

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