A stripping voltammetric method for Iodine Ion at chitosan incorporating carbon nanotubes modified electrode

被引:2
作者
Wang, ZongHua [1 ,2 ]
Wang, YuFeng [3 ]
Zhang, FeiFei [1 ,2 ]
Xia, YanZhi [1 ,2 ]
Xia, JianFei [1 ,2 ]
机构
[1] Qingdao Univ, Growing Base State Key Lab, Lab Fiber Mat & Modern Text, Qingdao, Peoples R China
[2] Qingdao Univ, Coll Chem & Environm Engn, Qingdao 266071, Peoples R China
[3] Qingdao Univ Sci & Technol, Coll Chem & Mol Engn, Qingdao 266042, Peoples R China
来源
ADVANCED RESEARCH ON ENVIRONMENTAL SCIENCE AND MATERIAL APPLICATION | 2012年 / 600卷
基金
中国国家自然科学基金;
关键词
Iodine ion; Chitosan; Carbon nanotubes (CNT); Modified electrode; DIRECT ELECTROCHEMISTRY; URIC-ACID; ADSORPTION; CHITIN;
D O I
10.4028/www.scientific.net/AMR.600.166
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
A novel chitosan incorporating carbon nanotubes coated electrode was constructed and applied to the differential pulse voltammetric (DPV) anodic stripping voltammetric characteristic's of iodine ion. The modified electrodes, exhibiting both of unique properties of CNT and chitosan, has excellent electrocatalytic effect of I-. The sensitive detection of iodine ion has been further improved. A linear calibration curve was obtained for 1x10(-6) mol/L to 1x10(-3) mol/L in 0.1 mol/L KH2PO4 buffer (pH = 4.0) with correlation coefficient of 0.998 and detection limit of 0.2 mu mol/L. The practical analytical application was illustrated by a measurement of iodine ion in salt.
引用
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页码:166 / +
页数:2
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