Golf ball-like particles fabricated by nonsolvent/solvent-induced phase separation method

被引:19
作者
Dai, Mingdong [1 ]
Song, Linyong [1 ]
Nie, Wangyan [1 ]
Zhou, Yifeng [1 ]
机构
[1] Anhui Univ, Anhui Prov Key Lab Environm Friendly Polymer Mat, Coll Chem & Chem Engn, Hefei, Peoples R China
关键词
Golf ball-like; Phase separation; Nonsolvent; Solvent; Reverse Pickering emulsion model; SILICA PARTICLES;
D O I
10.1016/j.jcis.2012.07.097
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Monodisperse poly(styrene-co-acrylic acid) (P(S-co-AA)) particles having a "golf ball-like" shape were prepared by nonsolvent/solvent-induced phase separation process. The method is simple and easy operation. The nonsolvent/solvent phase was mixture of butanol, n-heptane and toluene. The dimpled surface comes from the aggregation of oil droplets on the surface of polymer spheres. The dimple's morphology can be controlled by the polymer templates, dispersion medium, reaction time, and temperature. Reverse Pickering emulsion model was suggested for the formation of golf ball-like particles. (C) 2012 Elsevier Inc. All rights reserved.
引用
收藏
页码:168 / 171
页数:4
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