Charge transfer excited states sensitization of lanthanide emitting from the visible to the near-infra-red

被引：258

作者：

D'Aleo, Anthony ^{[2
]}

Pointillart, Fabrice ^{[1
]}

Ouahab, Lahcene ^{[1
]}

Andraud, Chantal ^{[3
]}

Maury, Olivier ^{[3
]}

机构：

[1] Univ Rennes 1, UMR CNRS Sci Chim Rennes UR1 6226, F-35042 Rennes, France

[2] Aix Marseille Univ, Ctr Interdisciplinaire Nanosci Marseille, UMR 7325, F-13288 Marseille 9 5, France

[3] Univ Lyon, Ecole Normale Super Lyon, CNRS, UMR 5182, F-69364 Lyon 07, France

来源：

COORDINATION CHEMISTRY REVIEWS | 2012年 / 256卷 / 15-16期

关键词：

Lanthanides; Luminescence; Design of ligands; Antenna effect; Intra-ligand charge transfers; Sensitization; Quantum yield; TRANSITION-METAL-COMPLEXES; INTRAMOLECULAR ENERGY-TRANSFER; II COORDINATION COMPLEX; RADICAL-CATION SALT; CU-II; EFFICIENT SENSITIZATION; CRYSTAL-STRUCTURE; EUROPIUM COMPLEX; MAGNETIC ANIONS; AQUO IONS;

D O I：

10.1016/j.ccr.2012.03.023

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Since the pioneering studies of Weissman in the 1940s, the sensitization of lanthanide luminescence via the antenna effect is becoming extremely classical. The photophysical sensitization process generally involves an energy transfer from the triplet excited state of an organic or a transition metal containing an antenna chromophore. Recently, the direct lanthanide sensitization from charge transfer excited state appears as an alternative process resulting in a red-shift of the excitation wavelength far in the visible thanks to the design of ligands with appropriate donor acceptor charge transfer transitions. This review presents the research endeavor in this area and underlines related applications in nonlinear optics. (C) 2012 Elsevier B.V. All rights reserved.

引用

页码：1604 / 1620

页数：17

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