New photochromic diarylethenes with a six-membered aryl unit

被引:99
作者
Pu, Shouzhi [1 ]
Fan, Congbin [1 ]
Miao, Wenjuan [1 ]
Liu, Gang [1 ]
机构
[1] Jiangxi Sci & Technol Normal Univ, Jiangxi Key Lab Organ Chem, Nanchang 330013, Peoples R China
基金
中国国家自然科学基金;
关键词
D O I
10.1016/j.tet.2008.07.073
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
A new class of photochromic diarylethenes bearing a six-membered aryl unit has been developed. They underwent reversible cyclization and cycloreversion reactions upon alternating irradiation with UV and visible light both in solution and in PMMA film. However, diarylethenes 1, 2, and 4 showed no photochromism in the crystalline phase although they packed with an anti-parallel conformation and the distances between the two reactive carbon atoms were both less than 4.2 angstrom. (C) 2008 Elsevier Ltd. All rights reserved.
引用
收藏
页码:9464 / 9470
页数:7
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