Rational regulation of transition metals in polyoxometalate hybrids without noble metal assistance for efficient light-driven H2production

被引：49

作者：

Li, Bonan ^{[1
]}

Yu, Xiaojing ^{[1
]}

Pang, Haijun ^{[1
]}

Shen, Qingbo ^{[1
]}

Hou, Yan ^{[1
]}

Ma, Jianjiao ^{[1
]}

Xin, Huiyuan ^{[1
]}

机构：

[1] Harbin Univ Sci & Technol, Coll Chem & Environm Engn, Sch Mat Sci & Engn, Harbin 150040, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2020年 / 56卷 / 52期

基金：

美国国家科学基金会;

关键词：

CATALYSTS;

D O I：

10.1039/d0cc00846j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Four new rationally designed polyoxometalate (POM)-based hybrids are reported with a maximum photocatalytic hydrogen evolution rate of 12245.59 mu mol g(-1)h(-1), which outperform all known POM-based metal-organic photocatalysts.

引用

页码：7199 / 7202

页数：4

共 18 条

[1] HETEROPOLYTUNGSTATES AS CATALYSTS FOR THE PHOTOCHEMICAL REDUCTION OF OXYGEN AND WATER [J].

AKID, R ;

DARWENT, JR .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1985, (02) :395-399

[2] Molecular artificial photosynthesis [J].

Berardi, Serena ;

Drouet, Samuel ;

Francas, Laia ;

Gimbert-Surinach, Carolina ;

Guttentag, Miguel ;

Richmond, Craig ;

Stoll, Thibaut ;

Llobet, Antoni .

CHEMICAL SOCIETY REVIEWS, 2014, 43 (22) :7501-7519

[3] ELECTROCHEMICAL PHOTOLYSIS OF WATER AT A SEMICONDUCTOR ELECTRODE [J].

FUJISHIMA, A ;

HONDA, K .

NATURE, 1972, 238 (5358) :37-+

[4] Highly dispersive bimetallic sulfides afforded by crystalline polyoxometalate-based coordination polymer precursors for efficient hydrogen evolution reaction [J].

Hou, Yan ;

Pang, Haijun ;

Zhang, Li ;

Li, Bonan ;

Xin, Jianjiao ;

Li, Kunqi ;

Ma, Huiyuan ;

Wang, Xinming ;

Tan, Lichao .

JOURNAL OF POWER SOURCES, 2020, 446

[5] Charge-regulated sequential adsorption of anionic catalysts and cationic photosensitizers into metal-organic frameworks enhances photocatalytic proton reduction [J].

Li, He ;

Yao, Shuang ;

Wu, Hong-Li ;

Qu, Jing-Yan ;

Zhang, Zhi-Ming ;

Lu, Tong-Bu ;

Lin, Wenbin ;

Wang, En-Bo .

APPLIED CATALYSIS B-ENVIRONMENTAL, 2018, 224 :46-52

[6] {Ta12}/{Ta16) Cluster-Containing Polytantalotungstates with Remarkable Photocatalytic H2 Evolution Activity [J].

Li, Shujun ;

Liu, Shumei ;

Liu, Shuxia ;

Liu, Yiwei ;

Tang, Qun ;

Shi, Zhan ;

Ouyang, Shuxin ;

Ye, Jinhua .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2012, 134 (48) :19716-19721

[7] Hydrophobic Polyoxometalate-Based Metal-Organic Framework for Efficient CO2 Photoconversion [J].

Li, Xiao-Xin ;

Liu, Jiang ;

Zhan, Lei ;

Dong, Long-Zhang ;

Xin, Zhi-Feng ;

Li, Shun-Li ;

Huang-Fu, Xue-Qing ;

Huang, Kai ;

Lan, Ya-Qian .

ACS APPLIED MATERIALS & INTERFACES, 2019, 11 (29) :25790-25795

[8] Engineering polyoxometalates with emergent properties [J].

Miras, Haralampos N. ;

Yan, Jun ;

Long, De-Liang ;

Cronin, Leroy .

CHEMICAL SOCIETY REVIEWS, 2012, 41 (22) :7403-7430

[9] Polyoxometalate-Based Metal Organic Frameworks (POMOFs): Structural Trends, Energetics, and High Electrocatalytic Efficiency for Hydrogen Evolution Reaction [J].

Nohra, Brigitte ;

El Moll, Hani ;

Rodriguez Albelo, L. Marleny ;

Mialane, Pierre ;

Marrot, Jerome ;

Mellot-Draznieks, Caroline ;

O'Keeffe, Michael ;

Biboum, Rosa Ngo ;

Lemaire, Joel ;

Keita, Bineta ;

Nadjo, Louis ;

Dolbecq, Anne .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2011, 133 (34) :13363-13374

[10] Earth-abundant cocatalysts for semiconductor-based photocatalytic water splitting [J].

Ran, Jingrun ;

Zhang, Jun ;

Yu, Jiaguo ;

Jaroniec, Mietek ;

Qiao, Shi Zhang .

CHEMICAL SOCIETY REVIEWS, 2014, 43 (22) :7787-7812

← 1 2 →