Gas-Phase Reactions in the ISM: Rate Coefficients, Temperature Dependences, and Reaction Products

被引：2

作者：

Smith, Ian W. M. ^{[1
]}

机构：

[1] Univ Cambridge, Dept Chem, Cambridge CB2 1EW, England

来源：

MOLECULAR UNIVERSE | 2011年 / 280期

关键词：

DENSE INTERSTELLAR CLOUDS; ION-NEUTRAL COLLISIONS; VERY-LOW TEMPERATURES; KINETICS; CHEMISTRY; SUPPLEMENT; MOLECULES; ATOMS;

D O I：

10.1017/S1743921311025117

中图分类号：

P1 [天文学];

学科分类号：

0704 ;

摘要：

Information about the rate coefficients and products of processes that occur in the interstellar medium are required as input to computer models that seek to reproduce the abundances of the rich variety of molecules that have been observed in different regions of the interstellar medium. In this brief review, I seek to identify the different kinds of gas-phase processes for which information is required and to consider the experimental, theoretical, and semi-empirical methods which are employed to measure or predict rate coefficients, k(T), and how they depend on temperature (T) - and also how the products of reactions can, in favourable cases, be observed.

引用

页码：361 / 371

页数：11

共 50 条

[41] Rate Constants for the Gas-Phase Reactions of Nitrate Radicals with Geraniol, Citronellol, and Dihydromyrcenol [J].

Harrison, Joel C. ;

Ham, Jason E. .

INTERNATIONAL JOURNAL OF CHEMICAL KINETICS, 2010, 42 (11) :669-675

[42] A theoretical study on the dynamics of gas-phase reaction of methyl cation with atomic oxygen [J].

Mousavi, Samaneh ;

Mousavipour, Seyed Hosein .

JOURNAL OF THE IRANIAN CHEMICAL SOCIETY, 2019, 16 (04) :807-825

[43] Can topological indices be used to predict gas-phase rate coefficients of importance to tropospheric chemistry? Free radical abstraction reactions of alkanes [J].

McGillen, MR ;

Percival, CJ ;

Raventos-Duran, T ;

Sanchez-Reyna, G ;

Shallcross, DE .

ATMOSPHERIC ENVIRONMENT, 2006, 40 (14) :2488-2500

[44] Experimental and theoretical rate coefficients for the gas phase reaction of β-Pinene with OH radical [J].

Dash, Manas Ranjan ;

Rajakumar, B. .

ATMOSPHERIC ENVIRONMENT, 2013, 79 :161-171

[45] Determination of gas-phase ozonolysis rate coefficients of a number of sesquiterpenes at elevated temperatures using the relative rate method [J].

Ghalaieny, Mohamed ;

Bacak, Asan ;

McGillen, Max ;

Martin, Damien ;

Knights, Alan V. ;

O'Doherty, Simon ;

Shallcross, Dudley E. ;

Percival, Carl J. .

PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2012, 14 (18) :6596-6602

[46] Rate coefficients for the gas-phase OH + furan (C4H4O) reaction between 273 and 353 K [J].

Angelaki, Maria E. ;

Romanias, Manolis N. ;

Burkholder, James B. ;

Papadimitriou, Vassileios C. .

INTERNATIONAL JOURNAL OF CHEMICAL KINETICS, 2024, 56 (03) :119-130

[47] Absolute Rate Coefficient of the Gas-Phase Reaction between Hydroxyl Radical (OH) and Hydroxyacetone: Investigating the Effects of Temperature and Pressure [J].

Vu, Ngoc Duy ;

Khamaganov, Victor ;

Nguyen, Vinh Son ;

Carl, Shaun A. ;

Peeters, Jozef .

JOURNAL OF PHYSICAL CHEMISTRY A, 2013, 117 (47) :12208-12215

[48] Temperature and pressure dependence of the rate coefficient for the reaction between ClO and CH3O2 in the gas-phase [J].

Leather, Kimberley E. ;

Bacak, Asan ;

Wamsley, Ruth ;

Archibald, Alexander T. ;

Husk, Alexander ;

Shallcross, Dudley E. ;

Percival, Carl J. .

PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2012, 14 (10) :3425-3434

[49] Rate Coefficients for the Gas-Phase Reaction of the Hydroxyl Radical with CH2=CHF and CH2=CF2 [J].

Baasandorj, Munkhbayar ;

Knight, Gary ;

Papadimitriou, Vassileios C. ;

Talukdar, Ranajit K. ;

Ravishankara, A. R. ;

Burkholder, James B. .

JOURNAL OF PHYSICAL CHEMISTRY A, 2010, 114 (13) :4619-4633

[50] Gas-Phase Ammonia Activation by Th, Th+, and Th2+ : Reaction Mechanisms, Bonding Analysis, and Rate Constant Calculations [J].

Niu, Wenxia ;

Zhang, Hong ;

Li, Peng ;

Gao, Tao .

INTERNATIONAL JOURNAL OF QUANTUM CHEMISTRY, 2015, 115 (01) :6-18

← 1 2 3 4 5 →